2,3-dimethylbutadiene sultone | 64931-18-6

分子结构分类

有机化合物 - 有机杂环化合物 - 氧硫杂环己烯

中文名称

——

中文别名

——

英文名称

2,3-dimethylbutadiene sultone

英文别名

4,5-dimethyl-3,6-dihydro-[1,2]oxathiin-2,2-dioxide；4,5-Dimethyl-3,6-dihydro-[1,2]oxathiin-2,2-dioxid；4,5-Dimethyl-3,6-dihydro-2H-1,2lambda~6~-oxathiine-2,2-dione；4,5-dimethyl-3,6-dihydrooxathiine 2,2-dioxide

CAS

64931-18-6

化学式

C₆H₁₀O₃S

mdl

——

分子量

162.21

InChiKey

KHMDWJRYZBWOLV-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

-0.3
重原子数：

10
可旋转键数：

0
环数：

1.0
sp3杂化的碳原子比例：

0.67
拓扑面积：

51.8
氢给体数：

0
氢受体数：

3

反应信息

作为反应物：

描述：

2,3-dimethylbutadiene sultone 在正丁基锂作用下，以乙醚、正己烷为溶剂，反应 0.25h，以98%的产率得到lithium 2,3-dimethyl-1Z-3-butadiene-1-sulfonate

参考文献：

名称：

Stereospecific synthesis of 1Z,3E-butadiene-1-sulfonic acids from ?,?-unsaturated ?-sultones and ?-sultams

摘要：

DOI：

10.1007/bf00960273
作为产物：

描述：

2,3-二甲基-1,3-丁二烯在三氧化硫、 1,2-二氯乙烷作用下，生成 2,3-dimethylbutadiene sultone

参考文献：

名称：

Sulfonation of Olefins. X. The Preparation of Tertiary 5- and 6-Membered Ring Sultones

摘要：

DOI：

10.1021/ja01517a054

点击查看最新优质反应信息

文献信息

Synthesis and properties of sulfoalkenyl amides

作者：I. M. Zaks、B. S. �l'ynov、V. M. Zhulin、A. M. Moiseenkov

DOI：10.1007/bf01141714

日期：1984.5
Electrochemical and chemical reduction of ?,?-unsaturated ?-cyclosulfonates

作者：S. G. Mairanovskii、A. M. Moiseenkov、I. V. Proskurovskaya、E. V. Polunin、V. P. Gul'tyai、I. M. Zaks、A. V. Semenovskii

DOI：10.1007/bf00946692

日期：1978.11
SEMENOVSKIJ A. V.; POLUNIN E. V.; ZAKS N. M.; MOISEENKOV A. M., IZV. AN CCCP. CEP. XIM., 1979, HO 6, 1327-13331

作者：SEMENOVSKIJ A. V.、 POLUNIN E. V.、 ZAKS N. M.、 MOISEENKOV A. M.

DOI：——

日期：——
ZAKS, I. M.;EHLYANOV, B. S.;ZHULIN, V. M.;MOISEENKOV, A. M., IZV. AN CCCP. CEP. XIM., 1984, N 5, 1094-1102

作者：ZAKS, I. M.、EHLYANOV, B. S.、ZHULIN, V. M.、MOISEENKOV, A. M.

DOI：——

日期：——
MOISEENKOV, A. M.;POLUNIN, E. V.;ZAKS, I. M., IZV. AN CCCP. CEP. XIM., 1984, N 12, 2751-2756

作者：MOISEENKOV, A. M.、POLUNIN, E. V.、ZAKS, I. M.

DOI：——

日期：——

同类化合物

6-乙氧基-2-甲基-5,6-二氢-1,4-氧硫杂环己二烯-3-羧酸 5,6-二氢-1,4-氧硫杂环己二烯-2-羧酸 5,6,7,8-四氢-4,7-二甲基-1,2-苯并氧硫杂环己二烯 2,2-二氧化物 2-甲基-5,6-二氢-1,4-氧硫杂环己二烯-3-甲酸 2-甲基-1,4-氧硫杂环己二烯-3-羧酸 1-(6-乙氧基-2-甲基-4-氧代-5,6-二氢-1,4-氧硫杂环己二烯-3-基)乙酮 1,4-苯并氧硫杂环己二烯4,4-二氧化物 1,4-氧硫杂环己二烯 1,4-噁噻英,2,3-二氢-5,6-二甲基- 1,2-苯并噁噻英,3,4-二氢- 1,2-氧硫杂环己二烯 methyl 6-chlorosulfonyl-3-methyl-1,2-benzoxathiin 2,2-dioxide ethyl benzo[e][1,2]oxathiine-3-carboxylate 2,2-dioxide N,N,N',N'-tetramethyl-N''-[2,2,2-trichloro-1-(5',6'-dihydro-2'-methyl-1',4'-oxathiin-3'-carboxamido)ethyl]phosphoric triamide 4-tert-butyl-1-(2,2-dioxido-1,2-benzoxathiin-6-yl)-1H-1,2,3-triazole 2-amino-4a,5,6,7,8,8a-hexahydrobenzo[b][1,4]oxathiine-3-carbonitrile 2,3-dihydro-2-methyl-2,6-diphenyl-1,4-oxathiin 2-[1-(2,2-dioxido-1,2-benzoxathiin-6-yl)-1H-1,2,3-triazol-4-yl]propan-2-ol 5,6-dihydro-[1,2]oxathiine 2,2-dioxide (+/-)-(2R,3R)-3-[(5-acetyl-6-methyl-2-prop-2-enyloxy-2H,3H-1,4-oxathiin-3-yl)methylthio]pentane-2,4-dione 2-propyl-3-(chloroethyl)-5,6-dihydro-1,4-oxathiin 3-(2-chlorobutyl)-5,6-dihydro-2-methyl-1,4-oxathiin 3-(2-chloroethyl)-5,6-dihydro-2-methyl-1,4-oxathiin 1-<5,6-dihydro-2-methyl-6-N-(2'-oxo-2',3',4',5'-tetrahydropyrrolo)-1,4-oxathiin-3-yl>ethanone 3-(2-chloroethyl)-5,6-dihydro-1,4-oxathiin 2-Butanone, 4-(4-hydroxy-2,2-dioxido-1,2-benzoxathiin-3-yl)-4-phenyl- Phosphorodithioic acid, S-2,3-dihydro-1,4-oxathiinyl O,O-dimethyl ester 4,7-Dimethyl-1,2,5,6,7,8-hexahydro-1-oxa-2-thianaphthalene 2,2-dioxide 4,5,6,7,8,9-hexahydro-1H-cyclohept[d][1,2]oxathiin-3-oxide 6,8-dichloro-1,2-benzoxathiine 2,2-dioxide 6-Morpholin-4-yl-2-phenyl-4,5,6,7-tetrahydro-9-oxa-1,8-dithia-3-aza-cyclopenta[a]naphthalene 8,8-dioxide 2-Phenyl-6-piperidin-1-yl-4,5,6,7-tetrahydro-9-oxa-1,8-dithia-3-aza-cyclopenta[a]naphthalene 8,8-dioxide ocimene sultone N,N-diisopropyl-3,4,5,6-tetrahydro-8-phenyl-1,2-oxathiino<5,6-g>benzothiazol-4-amine 2,2-dioxide N,N-dimethyl-3,4,5,6-tetrahydro-8-phenyl-1,2-oxathiino<5,6-g>benzothiazol-4-amine 2,2-dioxide 1,4-dimethyl-5,6,7,8-tetrahydro-benz[d][1,2]oxathiin-3,3-dioxide 2,2-dioxido-1,2-benzoxathiin-6-yl methanesulfonate (5,6-Dihydro-[1,4]oxathiin-2-yl)-acetic acid methyl ester acetic acid 2,2-dioxo-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester methanesulfonic acid 2,2-dioxo-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester acetic acid 2,2-dioxo-3,4-dihydro-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester methanesulfonic acid 2,2-dioxo-3,4-dihydro-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester ethyl 5,6-dihydro-2-trifluoromethyl-1,4-oxathiin-3-carboxylate 6-Phenyl-1,4-oxathiin-2-one 4-cyclopropyl-1-(2,2-dioxido-1,2-benzoxathiin-6-yl)-1H-1,2,3-triazole 4-(N,N-Diethylamino)-3,4,10,11-tetrahydro-5H-benzo-cyclohepta-1,2-oxathiin-2,2-dioxid (2,2-Dioxo-2,3,4,5,6,7-hexahydro-1-oxa-2λ⁶-thia-dibenzo[a,c]cyclohepten-4-yl)-diethyl-amine 6-methyl-4-pyrrolidin-1-yl-3,4,5,6,7,8-hexahydro-[1,2]oxathiino[5,6-c]pyridine 2,2-dioxide 6-methyl-4-piperidin-1-yl-3,4,5,6,7,8-hexahydro-[1,2]oxathiino[5,6-c]pyridine 2,2-dioxide 1-(2,2-Dioxo-6-phenyl-3,4-dihydro-2H-2λ⁶-[1,2]oxathiin-4-yl)-piperidine