4-[4'-(4-Acryloxybutoxy)benzoyloxy]phenol | 949114-36-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-[4'-(4-Acryloxybutoxy)benzoyloxy]phenol
• 英文别名: (4-hydroxyphenyl) 4-(4-prop-2-enoyloxybutoxy)benzoate
• CAS: 949114-36-7
• 化学式: C₂₀H₂₀O₆
• 分子量: 356.375
• InChiKey: JLACQKSTBXBZFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  26
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  82.1
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  草酰氯 、 4-(2-丙烯醛基氧基乙基-1-氧基)-苯甲酸 、 4-[4'-(4-Acryloxybutoxy)benzoyloxy]phenol 、 水 在 草酰氯 、 水 、 二氯甲烷 、 silica gel 、 toluene-ethyl acetate 作用下， 以 吡啶 、 甲苯 为溶剂， 反应 13.5h， 以giving 7.8 g (83%) of (4)的产率得到1-[4'-(4"-Acryloxybutoxy)benzoyloxy]-4-[4'-(2"-acryloxyethoxy)-benzoyloxy]benzene
  参考文献：
  名称：

  Polymerizable liquid-crystalline compounds

  摘要：

  本发明涉及液晶混合物，其包含至少两种不同的式I的物质：##STR1## 其中Z.sup.1和Z.sup.2分别独立地是可聚合基团，Y.sup.1和Y.sup.2分别独立地是直接键，--O--，--COO--，--OCO--或--S--，A.sup.1和A.sup.2分别独立地是间隔物，R.sup.1，R.sup.2和R.sup.3是常规取代基，以及上述式中至少有两个Z.sup.1，Z.sup.2，Y.sup.1，Y.sup.2，A.sup.1和A.sup.2不相同的新化合物。新混合物和化合物适用于彩色效应材料和压电材料的基材，特别是在手性掺杂形式下。

  公开号：

  US05833880A1
• 作为产物：
  描述：

  草酰氯 、 4-(4-(丙烯酰氧基)丁氧基)苯甲酸 、 对苯二酚 、 水 在 草酰氯 、 水 、 二氯甲烷 、 silica gel 、 toluene-ethyl acetate 作用下， 以 吡啶 、 甲苯 为溶剂， 反应 24.33h， 以giving 4.5 g (66%) of (3)的产率得到4-[4'-(4-Acryloxybutoxy)benzoyloxy]phenol
  参考文献：
  名称：

  Polymerizable liquid-crystalline compounds

  摘要：

  本发明涉及液晶混合物，其包含至少两种不同的式I的物质：##STR1## 其中Z.sup.1和Z.sup.2分别独立地是可聚合基团，Y.sup.1和Y.sup.2分别独立地是直接键，--O--，--COO--，--OCO--或--S--，A.sup.1和A.sup.2分别独立地是间隔物，R.sup.1，R.sup.2和R.sup.3是常规取代基，以及上述式中至少有两个Z.sup.1，Z.sup.2，Y.sup.1，Y.sup.2，A.sup.1和A.sup.2不相同的新化合物。新混合物和化合物适用于彩色效应材料和压电材料的基材，特别是在手性掺杂形式下。

  公开号：

  US05833880A1

文献信息

• Compound and liquid-crystal composition employing the same
  申请人：INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

  公开号：US10035956B2

  公开（公告）日：2018-07-31

  A compound and a liquid-crystal composition employing the same are provided. The compound has a structure represented by Formula (I) wherein Za and Zb are independently A1, A2, A3 and A4 are independently single bond, Z1, Z2, Z3, and Z4 are independently single bond, R is independently hydrogen, or C1-4 alkyl group; R1 and R2 are independently single bond, —O—(CH2)n—, —CH═CH—(CH2)2—, —(CH2)2—CH═CH—, —CH═CH—, or —C≡C—; n is an integer from 1 to 6; B1 and B2 are independently and, R3 is hydrogen, or methyl group.

  本研究提供了一种化合物和使用该化合物的液晶组合物。该化合物具有由式（I）表示的结构 其中 Za 和 Zb 分别独立为 A1、A2、A3 和 A4 都是独立的单键、 Z1、Z2、Z3 和 Z4 都是独立的单键、 R 独立地是氢、或 C1-4 烷基；R1 和 R2 独立地是单键、-O-(CH2)n-、-CH═CH-( )2-、-( )2-CH═CH-、-CH═CH- 或 -C≡C-；n 是 1-6 之间的整数；B1 和 B2 独立地是 R3为氢或甲基。
• NEUE POLYMERISIERBARE FLÜSSIGKRISTALLINE VERBINDUNGEN
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：EP0749466B1

  公开（公告）日：1997-11-12
• Compound, liquid crystal composition, and their applications
  申请人：Takeuchi Hiroshi

  公开号：US20070286968A1

  公开（公告）日：2007-12-13

  A novel compound is disclosed. The compound is represented by a formula (I) below: Q 1 -SP 1 —X 1 -A-B—C-D-X 2 —SP 2 -Q 2 (I) where, Q 1 and Q 2 respectively represent a polymerizable group; SP 1 and SP 2 respectively represent a spacer group; X 1 and X 2 respectively represent a linking group; and A, B, C and D respectively represent a divalent group selected from formulae IIa, IIb and IIc below: where, R a , R b and R c respectively represent a substituent group, na, nb and nc respectively represent an integer of 0 to 4, a plurality of R a , R b or R c may be same or different each other when na, nb and nc are respectively integers of 2 or more; provided that at least two of A, B, C and D is a divalent group represented by the formula IIa, or at least two of them is a divalent group represented by the formula IIb.
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, PHASE DIFFERENCE FILM AND LIQUID CRYSTAL DISPLAY USING THE SAME
  申请人：Tomita Hidetoshi

  公开号：US20100047478A1

  公开（公告）日：2010-02-25

  A polymerizable liquid crystal compound is represented by the following formula (1): P-Sp 1 -L 1 -M 1 -L 2 -Sp 2 -Ox   (1) wherein P represents a polymerizable group; one of Sp 1 and Sp 2 represents a branched alkylene group, or an alkylene group containing, in the chain thereof, at least one divalent linking group selected from the group consisting of —O—, —C≡C— and —S—; the other of Sp 1 and Sp 2 represents a straight chain alkylene group; each of L 1 and L 2 independently represents a divalent linking group; M 1 represents a mesogenic group; and Ox represents a substituent containing an oxetanyl group.
• LIQUID CRYSTAL COMPOSITION, METHOD FOR MANUFACTURING THE SAME, AND FILM
  申请人：FUJIFILM Corporation

  公开号：US20150191652A1

  公开（公告）日：2015-07-09

  A method for manufacturing a liquid crystal composition, the method including concurrently obtaining a liquid crystal compound represented by the formula (I) and a liquid crystal compound represented by the formula (II), by allowing a compound represented by the formula (III) to react with a carboxylic acid represented by the formula (IV) and a carboxylic acid represented by the formula (V), wherein P 1 represents a polymerizable group; Sp 1 represents a C 3-12 divalent aliphatic group, etc; T 1 represents a 1,4-phenylene group; T 2 represents a divalent group having a single bond or cyclic structure; A 1 represents —COO—, etc; A 2 and A 3 represents —OCO—, etc; X represents a hydrogen atom, C 1-12 alkyl group, etc; Y 1 and Y 2 represents O, NR 1 or S; R 1 represents a hydrogen atom or methyl group; Formula (I) P 1 -Sp 1 -T 1 -A 1 -B-A 2 -T 1 -Sp 1 -P 1 ; Formula (II) P 1 -Sp 1 -T 1 -A 1 -B-A 3 -T 2 -X; Formula (III) being HY 1 —B—Y 2 H; Formula (IV) P 1 -Sp 1 -T 1 -COOH; Formula (V) X-T 2 -COOH.