二氯甲基(1+) | 56932-33-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 中文名称: 二氯甲基(1+)
• 中文别名: 二氯甲基(1+)
• 英文名称: dichloromethyl(1+)
• 英文别名: dichloromethylium；Dichlormethan-kation；Dichlormethyl-Kation；Dichlormethylkation；dichloromethane
• CAS: 56932-33-3
• 化学式: CHCl₂
• 分子量: 83.9249
• InChiKey: LWGQYBCZRDWONC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.58
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  一溴二氯甲烷 以 neat (no solvent) 为溶剂， 生成 二氯甲基(1+)
  参考文献：
  名称：

  Harrison, A. G.; Shannon, T. W., Canadian Journal of Chemistry, 1962, vol. 40, p. 1730 - 1737

  摘要：

  DOI：

文献信息

• Gas-phase ion chemistry of titanium tetrachloride and methyltitanium chloride (CH3TiCl3). Reaction of CH3TiCl2+ with ethylene
  作者：Jack S. Uppal、Douglas E. Johnson、Ralph H. Staley

  DOI：10.1021/ja00393a005

  日期：1981.2
• Matrix‐Isolation Study of the Vacuum‐Ultraviolet Photolysis of Chloroform. Infrared Spectra of the CCl₃⁺, HCCl₂⁺, and HCCl₂⁻ Molecular Ions
  作者：Marilyn E. Jacox、Dolphus E. Milligan

  DOI：10.1063/1.1675449

  日期：1971.5

  Photolysis of samples of HCCl3 isolated in an argon matrix at 14°K using 1216-Å radiation leads not only to the isolation of a high yield of CCl3, but also to the photoionization of CCl3, resulting in the stabilization of a sufficient concentration of CCl3+ for direct infrared spectroscopic identification. The assignment of still other infrared absorptions which appear in this system to negatively charged species has been confirmed by experiments in which a small concentration of an alkali metal atom is also present in the matrix, providing a photoelectron source. When matrix-isolated HCCl3 is subjected to photolysis by 1067-Å argon resonance radiation, very little CCl3 is produced, but HCCl2, HCCl2+, and the same negatively charged species are stabilized in significant concentration. Studies of chloroform samples enriched in carbon-13 and of DCCl3 samples have provided support for these identifications and have yielded data necessary for obtaining several of the force constants of these species. The infrared spectrum of the negatively charged species can most satisfactorily be explained by postulating that dissociative electron attachment to chloroform occurs, resulting in the stabilization of HCCl2− in the matrix environment.
• Lossing, F. P., Bulletin des Societes Chimiques Belges, 1972, vol. 81, p. 125 - 134
  作者：Lossing, F. P.

  DOI：——

  日期：——
• An Electron-Impact Study of Ionization and Dissociation in Methoxy- and Halogen-Substituted Methanes¹
  作者：R. H. Martin、F. W. Lampe、R. W. Taft

  DOI：10.1021/ja00959a004

  日期：1966.4
• Chemical ionization mass spectrometry of halomethanes with tetramethylsilane as reagent gas
  作者：Oleg S. Chizhov、Valentin I. Kadentsev、Andrei A. Stomakhin

  DOI：10.1002/oms.1210270610

  日期：1992.6

  AbstractChemical ionization mass spectra of halomethanes measured using tetramethylsilane as reagent gas exhibit three major peaks corresponding to [M + SiMe3]+, [M − X]+ and (MeSi)2X+ ions (X = Cl, Br or I). Dihalomethanes CH2X2 form the most stable silylated molecular ions, whereas in the mass spectra of tetrahalomethanes (CX4) these ions have not been detected and the ions CX3+ are the most abundant. Production of bistrimethylsilyl‐halonium ions is the most pronounced process for haloforms (CHX3).