trans[tetraaquabis(5-nitriminotetrazolato-N4)]copper(II) | 1236273-78-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 亚胺内酰胺
• 英文名称: trans[tetraaquabis(5-nitriminotetrazolato-N4)]copper(II)
• CAS: 1236273-78-1
• 化学式: C₂H₁₀CuN₁₂O₈
• 分子量: 393.723
• InChiKey: RIVWTEDLVOHPHR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N-(2H-四唑-5-基)硝酰胺 、 copper(II) nitrate trihydrate 以 水 为溶剂， 以43%的产率得到trans[tetraaquabis(5-nitriminotetrazolato-N4)]copper(II)
  参考文献：
  名称：

  New energetic materials: Synthesis and characterization of copper 5-nitriminotetrazolates

  摘要：

  The energetic compounds 5-nitriminotetrazole (H2AtNO2, 1), 1-methyl-5-nitriminotetrazole (1MeHAtNO(2), 2) and 2-methyl-5-nitraminotetrazole (2MeHAtNO(2), 3), were reacted with Cu(NO3)(2) center dot 3H(2)O and CuCl2 center dot 2H(2)O, respectively, in water as well as in aqueous ammonia solution. The syntheses yielded the complexes [Cu(HAtNO2)(2)(H2O)(4)] (4), [Cu(AtNO2)(NH3)(3)](2) (5), (NH4)(2)[Cu(AtNO2)(2)(H2O)(2)] (6), [Cu(1MeAtNO(2))(2)(NH3)(2)] (7), [Cu((2)-MeAtNO2)(2)(2-MeHAtNO2)(2)] (8), [Cu(2MeAtNO(2))(2)](infinity) (9), [Cu(2-MeAtNO2) (2)(NH3)(2)] (10), and [Cu(2MeAtNO(2))(2)(NH3)(4)] center dot H2O (11). All complexes were characterized using low temperature single crystal X-ray diffraction, IR spectroscopy, elemental analysis, and differential scanning calorimetry. The magnetic properties of six of the complexes were investigated. Due to the energetic characters, the sensitivities towards impact and friction were investigated using the BAM drophammer and friction tester. The values range from "very sensitive", comparable to primary explosives, to "insensitive" depending on the amount of water or ammonia coordinated. Since Cu(II) salts can be used for colorants in pyrotechnics, the combustions and flame colors were discovered to be intensively green. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.10.014