Synthesis, Characterization and Properties of Asymmetrical Porphyrin with [p-Flourobenzoyl]-m-Ethyloxy] Phenyl and its Metal Complexes
摘要:
A new asymmetrical 5-[p-(4-flourobenzoyloxy)-m-ethyloxy] phenyl-10, 15, 20-triphenyl porphyrin and its transition metal (Zn, Cu, Ni, Co, Mn) complexes were synthesized. Their constitute and structure were characterized by elemental analyses, UV-vis, IR, molar conductances and 1H NMR. Optical properties were discussed by fluorescence spectrum, and their high thermal stability was explained by thermal analytical results.