4-(6-Acryloyloxy-hexyloxy)-benzoic acid 4-{2-[4-(6-acryloyloxy-hexyloxy)-phenyl]-ethyl}-phenyl ester | 852056-63-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-(6-Acryloyloxy-hexyloxy)-benzoic acid 4-{2-[4-(6-acryloyloxy-hexyloxy)-phenyl]-ethyl}-phenyl ester
• 英文别名: [4-[2-[4-(6-prop-2-enoyloxyhexoxy)phenyl]ethyl]phenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• CAS: 852056-63-4
• 化学式: C₃₉H₄₆O₈
• 分子量: 642.789
• InChiKey: QPGLDFRMPQKZSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  47
• 可旋转键数：
  26
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  97.4
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  N,N'-二环己基碳二亚胺 、 4-{2-[4-(6-Acryloyloxy-hexyloxy)-phenyl]-ethyl}-phenol 、 4-(6-(丙烯酰氧基)己氧基)苯甲酸 、 在 ice 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以2.3 g of 4-(6-Acryloyloxy-hexyloxy)-benzoic acid 4-{2-[4-(6-acryloyloxy-hexyloxy)-phenyl]-ethyl}-phenyl ester (10, 78%) was obtained的产率得到4-(6-Acryloyloxy-hexyloxy)-benzoic acid 4-{2-[4-(6-acryloyloxy-hexyloxy)-phenyl]-ethyl}-phenyl ester
  参考文献：
  名称：

  DICHROIC GUEST-HOST POLARIZER COMPRISING AN ORIENTED POLYMER FILM

  摘要：

  一种二色性客体-主体偏振器包括定向聚合液晶主体和与之对齐的二色性客体。该偏振器的二色性比约为15或更高。该偏振器可以具有较小的厚度，使用湿法沉积方法制造，可选地按所需模式，并在液晶电池的内部提供。揭示了具有高度有序介相的可聚合液晶，可用于获得高度定向的聚合物薄膜，如偏振器薄膜。

  公开号：

  US20100267858A1

文献信息

• OPTICAL FILM
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20170305930A1

  公开（公告）日：2017-10-26

  Provided is an optical film which has a maximum absorption at a wavelength in the range of 600 to 680 nm, has a high dichroic ratio, and is excellent in light resistance. The optical film includes: a polymer of a polymerizable liquid crystal compound; and a compound represented by the following general formula (1).

  提供的是一种光学膜，其在波长范围为600到680纳米处具有最大吸收，具有高二向比，并且在光抗性方面表现优异。该光学膜包括：聚合物可聚合液晶化合物；以及下列一般式（1）所代表的化合物。
• DICHROIC DYE COMPOUND, POLARIZING FILM, AND USES THEREOF
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20170226071A1

  公开（公告）日：2017-08-10

  A compound having a maximum absorption in a wavelength range of 350 nm to 550 nm that functions as a dichroic dye is provided. In particular, a compound represented by formula (1) is provided. In the compound of formula (1), R 1 represents an alkyl group having 1 to 20 carbon atoms or the like; R 2 represents an acyl group having 1 to 20 carbon atoms or the like; R 3 represents a hydrogen atom or the like; and Y represents a group of formula (Y1). In the formula (Y1), * represents a bonding site with N, or a group of formula (Y2). In the formula (Y2), * represents a bonding site with N; P 1 and P 2 each independently represent —S— or the like; and Q 1 and Q 2 each independently represent ═N— or the like.

  提供一种在波长范围为350nm至550nm具有最大吸收并作为二色染料的化合物。特别地，提供一种由公式（1）表示的化合物。在公式（1）的化合物中，R1表示具有1至20个碳原子的烷基或类似物；R2表示具有1至20个碳原子的酰基或类似物；R3表示氢原子或类似物；Y表示公式（Y1）的基团。在公式（Y1）中，*表示与N的连接位点，或者是公式（Y2）的基团。在公式（Y2）中，*表示与N的连接位点；P1和P2各自独立地表示—S—或类似物；Q1和Q2各自独立地表示═N—或类似物。
• COMPOUND AND COMPOSITION CONTAINING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20180072890A1

  公开（公告）日：2018-03-15

  A compound serving as a dichroic pigment which has a maximum absorption wavelength in a range of 350 nm to 510 nm is represented by the following Formula (1): In Formula (1), R 1 represents a hydrogen atom or a C1-C20 alkyl group; R 2 through R 4 are substituents which are not hydrogen atoms and each independently represent a C1-C4 alkyl group; m, p, and q are each independently an integer of 0 to 2; and R 5 is (i) a C1-C10 alkyl group in which a hydrogen atom is substituted by at least one hydroxy group or (ii) a C1-C10 alkyl group which has carbon atoms and in which at least one —O— is inserted between the carbon atoms.

  化合物作为二色性颜料，其最大吸收波长在350纳米至510纳米范围内，由以下式（1）表示： 在式（1）中，R1表示氢原子或C1-C20烷基；R2至R4是不是氢原子的取代基，每个独立地表示C1-C4烷基；m，p和q分别是0至2的整数；R5是（i）C1-C10烷基，其中至少一个氢原子被羟基取代或（ii）C1-C10烷基，其中至少有一个-O-插入碳原子之间。
• Dichroic guest-host polarizer comprising an oriented polymer film
  申请人：Lub Johan

  公开号：US20070024970A1

  公开（公告）日：2007-02-01

  A dichroic guest-host polarizer comprises an oriented polymerized liquid crystal host and aligned therewith a dichroic guest. The dichroic ratio of the polarizer is about 15 or more. The polarizer may have a small thickness, be manufactured using a wet deposition method, optionally in accordance with a desired pattern, and be provided on the inside of a liquid crystal cell. Polymerizable liquid crystals having a highly ordered mesophase which may be suitable used to obtain highly oriented polymer films such as polarizer films are disclosed.

  一种二色性客体-宿主偏振器包括定向的聚合液晶宿主和与之对齐的二色性客体。偏振器的二色比约为15或更高。该偏振器可以具有较小的厚度，可以使用湿法沉积方法制造，可以根据所需的图案进行制造，并放置在液晶电池的内部。揭示了具有高度有序介相的可聚合液晶，可用于获得高度定向的聚合物薄膜，例如偏振器薄膜。
• Composition and polarizing film
  申请人：Sumitomo Chemical Company, Limited

  公开号：US10005960B2

  公开（公告）日：2018-06-26

  Provided is a composition which is to be a raw material of a polarizing film having excellent light fastness. The composition includes a polymerizable liquid crystal compound and a compound represented by the following formula (1): wherein E represents an electron attractive group having at least 3 carbon atoms or the following group: wherein R represents a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms; Ar represents a group selected from the following groups: and A represents a group selected from the following groups: wherein R2, R3 and R4, and l, m, n, p, and q are defined in the specification.

  本发明提供了一种组合物，该组合物可作为具有优异耐光性的偏光膜的原料。该组合物包括一种可聚合液晶化合物和一种由下式（1）表示的化合物： 其中 E 代表至少有 3 个碳原子的引电子基团或以下基团： 其中 R 代表氢原子或具有 1 至 20 个碳原子的烃基； Ar 代表选自以下基团的一个基团： 和 A 代表选自以下组别的一个基团： 其中 R2、R3 和 R4 以及 l、m、n、p 和 q 的定义见说明书。