| 158791-13-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• CAS: 158791-13-0
• 化学式: C₃₂H₂₆N₂O₂Sn
• 分子量: 589.281
• InChiKey: SWLWLMZEVNCXFZ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  三苯基氯化锡 、 2-hydroxy-5-(p-tolyldiazenyl)benzaldehyde 在 triethyl amine 作用下， 以 苯 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Characterization of some triphenyltin(IV) complexes of 5-(arylazo)salicylaldehyde ligands using IR, 1H, 13C, 119Sn NMR and 119Sn Mössbauer spectroscopy

  摘要：

  Coordination complexes of 5-(arylazo)salicylaldehyde with triphenyltin chloride have been prepared and subjected to IR, multinuclear NMR (H-1, C-13, Sn-119) and Sn-119 Mossbauer spectroscopy. 5-(Arylazo)salicylaldehyde forms two types of complexes viz. triorganotin adducts and phenoxides. In the adducts. the protonated ligand coordinates through the aldehydic oxygen atom while in phenoxides, the coordination occurs via the phenolic oxygen atom and the oxygen atom of the aldehydic group. The spectroscopic data suggest that both types of complexes adopt a cis-trigonal bipyramidal geometry around tin.

  DOI：

  10.1016/s0277-5387(00)81506-5