| 39630-96-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• CAS: 39630-96-1
• 化学式: F₄OU
• 分子量: 330.022
• InChiKey: GYTWQRKEJAQWIA-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  (NEt₄)₂[(UO₂)₄F₁₀(H₂O)₃] 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10]

  摘要：

  A new uranyl oxyfluoride, [N(C2H5)(4)](2)(UO2)(4)(OH2)(3)F-10] has been synthesized by a hydrothermal reaction technique using (C2H5)(4)NBr, UO2(OCOCH3)(2)center dot 2H(2)O, and HF as reagents. The structure of [N(C2H5)(4)[(2)[(UO2)(4)(OH2)(3)F-10] has been determined by a single-crystal X-ray diffraction technique. [N(C2H5)(4)](2)(UO2)(4)(OH2)(3)F-10] crystallizes in the monoclinic space group P2(1)/n (No. 14), with a = 13.852(3) angstrom, b = 15.532(3) angstrom, c = 16.481(3) angstrom, beta = 98.88(3)degrees, V = 3503.4(12) angstrom(3), and Z = 4. [N(C2H5)(4)](2)(UO2)(4)(OH2)(3)F-10] reveals a novel pseudo-two-dimensional crystal structure that is composed of UO2F5, UO3F4, and UO4F3 pentagonal bipyramids. Each uranyl pentagonal bipyramid shares edges and corners through F atoms to form a six-membered ring. The rings are further interconnected to generate infinite strips running along the b-axis. [N(C2H5)(4)](2)(UO2)(4)(OH2)(3)F-10] has been further characterized by elemental analysis, bond valence calculations, Infrared and Raman spectroscopy, and thermogravimetric analysis. (c) 2006 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2006.11.004

文献信息

• The preparation and properties of AgUF6 and AgUOF5
  作者：John G. Malm

  DOI：10.1016/0022-1902(80)80389-7

  日期：1980.1

  AgUF6 and AgUOF5 are formed by precipitation from liquid hydrogen fluoride. Chemical and physical properties are described.

  AgUF 6和AgUOF 5通过从液态氟化氢中沉淀而形成。描述了化学和物理性质。