[6-nitro-12,14-dimethyl-3,9-bis(propylsulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14-hexaenato(2-)-N(1),N(4),N(8),N(11)]nickel(II) | 139028-59-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吖庚因类
• 英文名称: [6-nitro-12,14-dimethyl-3,9-bis(propylsulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14-hexaenato(2-)-N(1),N(4),N(8),N(11)]nickel(II)
• CAS: 139028-59-4
• 化学式: C₁₆H₂₃N₇NiO₂S₂
• 分子量: 468.226
• InChiKey: SKLPXEQZNLWPOH-BUBOXAAXSA-N

反应信息

• 作为产物：
  描述：

  、 以 甲醇 为溶剂， 以18%的产率得到[6-nitro-12,14-dimethyl-3,9-bis(propylsulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14-hexaenato(2-)-N(1),N(4),N(8),N(11)]nickel(II)
  参考文献：
  名称：

  The crystal structures of [6-nitro-12,14-dimethyl-3,9-bis(propylsulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12, 14-hexaenato(2-)-N1, N4, N8, N11]nickel(II) and [12,14-dimethyl-3,9-bis(ethylsulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14- hexaenato(2-)-N1, N4, N8, N11]nickel(II)

  摘要：

  Hexaazamocrocyclic complexes [6-nitro-12,14-dimethyl-3,9-bis(sulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14-hexaenato(2-)-N-1,N-4,N-8,N-11]nickel(II) and [12,14-dimethyl-3,9-bis(ethylsulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14-hexaenato(2-)-N-1,N-4,N-8,N-11]nickel(II) have been synthesized by a template procedure starting from an open-chain precursor. The crystal structure of both macrocycle products showed a square planar coordination geometry with cis-positioned-SR groups relative to the nickel atom.

  DOI：

  10.1016/0277-5387(94)00284-l

文献信息

• Gerbeleu, N. V.; Gredinaru, D. I.; Arion, V. B., Russian Journal of Inorganic Chemistry, 1991, vol. 36, p. 54 - 56
  作者：Gerbeleu, N. V.、Gredinaru, D. I.、Arion, V. B.、Indrichan, K. M.

  DOI：——

  日期：——