bis(2-benzoylpyridine)dichlorocadmium(II) | 1161915-86-1

• 英文名称: bis(2-benzoylpyridine)dichlorocadmium(II)
• 英文别名: {Cd(2-benzoylpyridine)2Cl2}
• CAS: 1161915-86-1；123047-69-8
• 化学式: C₂₄H₁₈CdCl₂N₂O₂
• 分子量: 549.735
• InChiKey: NMKQIBJNMAHFMB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-苯甲酰吡啶 、 aqueous cadmium chloride 以 甲醇 、 水 为溶剂， 以80%的产率得到bis(2-benzoylpyridine)dichlorocadmium(II)
  参考文献：
  名称：

  Experimental and computational investigations of cadmium(II) complexes incorporating 2-benzoylpyridine

  摘要：

  Three novel cadmium(II) complexes of 2-benzoylpyridine [Cd(bopy)(2)Cl-2] (1). {[Cd(bopy)(mu(1,1)-N-3)(2)]center dot bopy}(n) (2) and [Cd(bopy)(2)(SCN)(2)] (3) were synthesized and characterized by spectroscopic and crystallographic methods. Azide ions of 2 act as bridging ligands generating a 1D chain running along [0 1 0]. The zig-zag chains consisting of {Cd(bopy)(N-3)(2)} units are separated by 2-benzoylpyridine molecules. The fluorescence properties of the complexes 1.2 and 3 were examined both in solid state and solution, and compared with the free ligand. Additionally, the electronic spectrum of 3 were investigated at the TDDFT level employing B3LYP functional in combination with LANL2DZ. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.06.007

文献信息

• Das; Roy, Journal of the Indian Chemical Society, 1989, vol. 66, # 5, p. 332 - 333
  作者：Das、Roy

  DOI：——

  日期：——