[zinc(II)(2,2'-bipyridine)(N,N'-bis(salicylidene)-p-phenylenediamine)]2 | 791845-30-2

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 醌二甲烷类
• 英文名称: [zinc(II)(2,2'-bipyridine)(N,N'-bis(salicylidene)-p-phenylenediamine)]2
• 英文别名: [Zn(2,2'-bipyridine)(N,N'-bis(salicylidenato)-p-phenylenediamine)]2；[Zn(bpy)(N,N'-bis(salicylidenato)-p-phenylenediamine)]2
• CAS: 791845-30-2
• 化学式: C₆₀H₄₄N₈O₄Zn₂
• 分子量: 1071.84
• InChiKey: QQCSYDAZPCJLEA-QSEGVIKWSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  六氟苯 、 [zinc(II)(2,2'-bipyridine)(N,N'-bis(salicylidene)-p-phenylenediamine)]2 在 NH₄PF₆ 作用下， 以 甲醇 、 水 、 二甲基亚砜 为溶剂， 以36%的产率得到[Zn(2,2'-bipyridine)(N,N'-bis(salicylidenato)-p-phenylenediamine)]2*hexafluorobenzene
  参考文献：
  名称：

  Reactivity of M(en)Cl2 (M=PdII/PtII, en=1,2-diaminoethane) with N,N′-bis(salicylidene)-p-phenylenediamine: Binding with hexafluorobenzene

  摘要：

  Schiff base N,N'-bis(salicylidene)-p-phenytenediamine (LH2) complexed with Pt(en)Cl-2 and Pd(en)Cl-2 provided [Pt(en)L](2).4PF(6) (1) and Pd(Salen) (2) (Salen = N,N'-bis(salicylidene)-ethylenediamine), respectively, which were characterized by their elemental analysis, spectroscopic data and X-ray data. A solid complex obtained by the reaction of hexafluorobenzene (hfb) with the representative complex I has been isolated and characterized as 3 (1 - hfb) using UV-Vis, NMR (H-1, C-13 and F-19) data. A solid complex of hfb with a reported Zn-cyclophane 4 has also been prepared and characterized 5 (4 - hfb) for comparison with complex 3. The association of hfb with 1 and 4 has also been monitored using UV-Vis and luminescence data. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.09.017

文献信息

• Kumari, Niraj; Prajapati, Rishikesh; Dixit, Mudit, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2009, vol. 48, # 12, p. 1644 - 1651
  作者：Kumari, Niraj、Prajapati, Rishikesh、Dixit, Mudit、Mishra, Lallan

  DOI：——

  日期：——