[((Cp(ttt))2Tm)2(μ-(1,1'-bis(1,4-dihydropyridylamide)] | 945421-53-4

• 英文名称: [((Cp(ttt))2Tm)2(μ-(1,1'-bis(1,4-dihydropyridylamide)]
• 英文别名: [((1,2,4-tris(tert-butyl)cyclopentadienyl)2Tm)2(μ-(1,1'-bis(1,4-dihydropyridylamide)))]
• CAS: 945421-53-4
• 化学式: C₇₈H₁₂₆N₂Tm₂
• 分子量: 1429.74
• InChiKey: SZTUKGNLDMNZAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 Tm(tris-tert-butylcyclopentadienyl)2 以 甲苯 为溶剂， 以10%的产率得到[((Cp(ttt))2Tm)2(μ-(1,1'-bis(1,4-dihydropyridylamide)]
  参考文献：
  名称：

  二价Th与环戊二烯基和磷脂基配体的有机金属配合物的合成和反应性

  摘要：

  Reaction of sodium 1,2,4-tris(trimethylsilyl)cyclopentadienide [Na(Cp' '')] with [TmI2(THF)(3)] afforded the divalent thulium complex [(Cp' '')(2)Tm(THF)]. Its crystal structure is similar to that of the previously described [(Cp-ttt)(2)Tm(THF)] (Cp-ttt = 1,2,4-tris(tert-butyl)cyclopentadienyl). [(Cp' '')(2)TmI] was prepared by reaction of TmI3 with [K(Cp' '')] and could be reduced by KC8 into a new unsolvated, homoleptic complex, [(Cp' '')(2)Tm], which was characterized by NMR. [(Cp' '')(2)Tm] gave [(Cp' '')(2)Tm(THF)] by interaction with THF. A convenient alternative pathway to [(Cp-ttt)(2)Tm] by reduction of [(Cp-ttt)(2)Tm(BH4)] with KC8 was found: [(Cp-ttt)(2)Tm(BH4)] derives from [Tm(BH4)(3)(THF)(3)], which can be prepared from the less expensive TmCl3. On the other hand, the dimer [{(Cp-tt)(2)TmI}(2)] (Cp-tt = 1,3-bis(tert-butyl)cyclopentadienyl), obtained by reaction of TmI3 with [Na(Cp-tt)], gave only intractable results by reaction with KC8. The previously described Tm-II complex [(Dtp)(2)Tm] (Dtp = 2,5-di-tert-butyl-3,4-dimethylphospholyl) and the new, homoleptic, structurally characterized Tm-II dimer [{(Htp)(2)Tm}(2)] (Htp = 2,5-di-tert-butylphospholyl) were prepared by KC8 reduction of [(Dtp)(2)TmI] and [{(Htp)(2)TmI}(2)], respectively. Reaction of [(Cp-ttt)(2)Tm] with pyridine resulted in an immediate reduction of pyridine into 1,1'-bis(1,4-dihydropyridylamide) and the formation of the structurally characterized [{(Cp-ttt)(2)Tm}(2){mu-(NC5H5-C5H5N)}], while the reaction of [(Dtp)(2)Tm] with pyridine gave no isolable complexes. An NMR study suggests that initially a simple Tm-II adduct such as [(Dtp)(2)Tm(pyridine)] is formed in this reaction.

  DOI：

  10.1021/om700316a