(2R)-diisopropyl-3-methyl-2-pyrrolidin-1-yl-butyl phosphite | 392234-66-1

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: (2R)-diisopropyl-3-methyl-2-pyrrolidin-1-yl-butyl phosphite
• CAS: 392234-66-1
• 化学式: C₁₅H₃₂NO₃P
• 分子量: 305.398
• InChiKey: YNKCURNRROXQPE-OAHLLOKOSA-N

物化性质

• 沸点：
  336.1±25.0 °C(Predicted)

反应信息

• 作为反应物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 (2R)-diisopropyl-3-methyl-2-pyrrolidin-1-yl-butyl phosphite 以 二氯甲烷 为溶剂， 以95%的产率得到((2R)-diisopropyl 3-methyl-2-pyrrolidin-1-yl-butyl phosphite-P,N)chlorocarbonyl rhodium(I)
  参考文献：
  名称：

  Phosphite derivatives of (2R)-2-pyrrolidin-1-yl-butan-1-ol: synthesis, chelation with rhodium(I) and testing in the palladium-catalysed allylic alkylation

  摘要：

  A series of chiral phosphite-type ligands with pyrrolidine moieties was synthesised. The compounds form chelate complexes upon reaction with [Rh(CO)(2)Cl](2). The new ligands were tested in Pd-catalysed enantioselective allylic alkylation giving up to 61% ee under standard conditions. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00583-7