(3aS,5aR,10bR,12bS)-9-Bromo-3a-ethyl-5-oxo-2,3,3a,5,5a,11,12,12b-octahydro-1H,4H-6,12a-diaza-indeno[7,1-cd]fluorene-6-carboxylic acid methyl ester | 111967-35-2

分子结构分类

有机化合物 - 生物碱及其衍生物 - 冬青素型生物碱

中文名称

——

中文别名

——

英文名称

(3aS,5aR,10bR,12bS)-9-Bromo-3a-ethyl-5-oxo-2,3,3a,5,5a,11,12,12b-octahydro-1H,4H-6,12a-diaza-indeno[7,1-cd]fluorene-6-carboxylic acid methyl ester

英文别名

——

(3aS,5aR,10bR,12bS)-9-Bromo-3a-ethyl-5-oxo-2,3,3a,5,5a,11,12,12b-octahydro-1H,4H-6,12a-diaza-indeno[7,1-cd]fluorene-6-carboxylic acid methyl ester化学式

CAS

111967-35-2

化学式

C₂₁H₂₅BrN₂O₃

mdl

——

分子量

433.345

InChiKey

KEHMEDLULKDYSS-QIJZPMMNSA-N

BEILSTEIN

——

EINECS

——

反应信息

作为产物：

描述：

(3aS,5S,5aR,10bR,12bS)-9-Bromo-3a-ethyl-5-nitro-2,3,3a,5,5a,11,12,12b-octahydro-1H,4H-6,12a-diaza-indeno[7,1-cd]fluorene-6-carboxylic acid methyl ester 在盐酸作用下，以甲醇为溶剂，反应 3.0h，以58%的产率得到(3aS,5aR,10bR,12bS)-9-Bromo-3a-ethyl-5-oxo-2,3,3a,5,5a,11,12,12b-octahydro-1H,4H-6,12a-diaza-indeno[7,1-cd]fluorene-6-carboxylic acid methyl ester

参考文献：

名称：

Nitroindolenines en serie vincadifformine : intermediaires d'acces a la vincamone et a un squelette azahomoaspidospermane

摘要：

DOI：

10.1016/s0040-4020(01)89982-8

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老刺木素洛柯因桥替啶坚木碱吡啶-3,4-二羧酸酐 21,O-seco-21,O-Dihydro-hedrantherin 17-methoxy-21-phenoxy-1-propionyl-aspidospermidine N(a)-Methyl-eburinol 2-Hydroxy-3-acetoxymethyl-2-desoxo-3-desmethyoxycarbonyl-vincatin 17-methoxy-21-phenoxy-aspidospermidine 16,17,16',17'-tetraacetoxy-1,1'-diacetyl-[15,15']biaspidospermidinyl 21,0-seco-21,0-Dihydro-17-methoxy-hedrantherin 16-Epi-eburinol 2-Hydroxy-3-hydroxymethyl-2-desoxo-3-desmethyoxycarbonyl-vincatin Vincamsonine Folicangine (-)-14β-hydroxyervinceine Dihydro-obscurinervidindiol-monoacetat O-(p-Jod)benzoyl-demethylvobtusin Ethyl-10-brom-vincadifformat 14-hydroxyervinceine 8-cyano-2,3-didehydro-aspidospermidine-3-carboxylic acid methyl ester Dihydro-neblininolon-acetat Dihydrocimicin 14β-acetoxyvincadifformine 3-acetoxymethyl-1-acetyl-aspidospermidine 15-bromo-16-methoxy-1-methyl-10-oxo-3,4-didehydro-aspidospermidine-3-carboxylic acid methyl ester (6R,6aS,7S,8R,9S)-8-acetoxy-7-ethyl-13a-hydroxy-6-(methoxycarbonyl)-6,7,8,9,10,12,13,13a-octahydro-6,9-methanopyrido[1',2':1,2]azepino[4,5-b]indole 11(6aH)-oxide Dihydrocimicidin jerantinine E acetate Dihydro-neblinin (IIf) 17-hydroxy-1-propionyl-aspidospermidin-21-oic acid methyl ester 3-hydroxymethyl-1-methyl-aspidospermidin-7-ol 3,4-diacetoxy-16-methoxy-1-methyl-10-oxo-aspidospermidine-3-carboxylic acid methyl ester Vincadifformindol 15-bromo-2,20-cyclo-aspidospermidine-3-carboxylic acid methyl ester 7-thioxo-2,3-didehydro-aspidospermidine-3-carboxylic acid ethyl ester Tetrahydrohaplophytin II 16,17,16',17'-tetramethoxy-1',2'-didehydro-[1,15']biaspidospermidinyl 7-oxo-2,3-didehydro-aspidospermidine-3-carboxylic acid ethyl ester Tetrahydroaspidophytin-methylester 20-bromo-2,3-didehydro-aspidospermidine-3-carboxylic acid methyl ester 8-oxo-aspidospermidine-3-carboxylic acid methyl ester 2-Cyano-19-ethoxycarbonyl-19-demethylaspidospermidine Tetrahydrohaplophytin II Methylester 6-hydroxy-1-methyl-aspidospermidine-3-carboxylic acid methyl ester 6-acetoxy-1-methyl-aspidospermidine-3-carboxylic acid methyl ester

(3aS,5aR,10bR,12bS)-9-Bromo-3a-ethyl-5-oxo-2,3,3a,5,5a,11,12,12b-octahydro-1H,4H-6,12a-diaza-indeno[7,1-cd]fluorene-6-carboxylic acid methyl ester | 111967-35-2

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