trans-bis(1,3-bis-(dimethylphosphino)propane)iron dichloride | 142711-45-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 磷环化合物
• 英文名称: trans-bis(1,3-bis-(dimethylphosphino)propane)iron dichloride
• CAS: 142711-45-3
• 化学式: C₁₄H₃₆Cl₂FeP₄
• 分子量: 455.088
• InChiKey: FYQYPTKPJMRJLF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  21.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  trans-bis(1,3-bis-(dimethylphosphino)propane)iron dichloride 、 1,2-双(二甲基瞵)乙烷 以 not given 为溶剂， 生成 (dmpe)₂FeCl₂
  参考文献：
  名称：

  Preparation and X-ray crystal structure of Fe(Me2PCH2CH2CH2CH2PMe2)2Cl2

  摘要：

  The bidentate ligand (CH3)2PCH2CH2CH2P(CH3)2 [DMPP = 1,3-bis-(dimethylphosphino)propane] was an unexpected product arising from the photochemical addition of dimethylphosphine to triallylphosphine. Addition of FeCl2 afforded the corresponding dichloride complex trans-Fe(DMPP)2Cl2 which was partially reduced to the cis-hydrochloride complex Fe(DMPP)2HCl and then to the cis-dihydride complex Fe(DMPP)2H2. The properties of Fe(DMPP)2Cl2, Fe(DMPP)2HCl and Fe(DMPP)2H2, including the X-ray structure of trans-Fe(DMPP)2Cl2, are reported.

  DOI：

  10.1016/s0277-5387(00)86931-4
• 作为产物：
  描述：

  1,3-二(联苯基膦)丙烷 、 iron(II) chloride 以 乙醇 、 甲苯 为溶剂， 生成 (P(CH2CH2CH2P(CH3)2)3)iron dichloride 、 trans-bis(1,3-bis-(dimethylphosphino)propane)iron dichloride
  参考文献：
  名称：

  Preparation and X-ray crystal structure of Fe(Me2PCH2CH2CH2CH2PMe2)2Cl2

  摘要：

  The bidentate ligand (CH3)2PCH2CH2CH2P(CH3)2 [DMPP = 1,3-bis-(dimethylphosphino)propane] was an unexpected product arising from the photochemical addition of dimethylphosphine to triallylphosphine. Addition of FeCl2 afforded the corresponding dichloride complex trans-Fe(DMPP)2Cl2 which was partially reduced to the cis-hydrochloride complex Fe(DMPP)2HCl and then to the cis-dihydride complex Fe(DMPP)2H2. The properties of Fe(DMPP)2Cl2, Fe(DMPP)2HCl and Fe(DMPP)2H2, including the X-ray structure of trans-Fe(DMPP)2Cl2, are reported.

  DOI：

  10.1016/s0277-5387(00)86931-4