4,8-二甲基-2-磷酸双环[3.3.1]壬烷 | 328952-85-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 磷环化合物
• 中文名称: 4,8-二甲基-2-磷酸双环[3.3.1]壬烷
• 英文名称: 4,8-Dimethyl-2-phosphabicyclo[3.3.1]nonane
• CAS: 328952-85-8
• 化学式: C₁₀H₁₉P
• 分子量: 170.23
• InChiKey: ZFQDZRKZDDYFJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Single component cationic palladium proinitiators for the latent polymerization of cycloolefins
  申请人：Bell Andrew

  公开号：US20050187398A1

  公开（公告）日：2005-08-25

  Palladium compound compositions are provided in accordance with Formulae [((R) 3 E) a Pd(Q)(LB) b ] p [WCA] r , where ((R) 3 E) is a Group 15 electron donor ligand, Q is an anionic ligand, LB is a Lewis base, WCA is a weakly coordinating anion, a is 1, 2 or 3, b is 0, 1 or 2, the sum of a and b is 1, 2 or 3 and each of p and r is an integer such that the molecular charge is zero, or [(E(R) 3 )(E(R) 2 R*)Pd(LB)] p [WCA] r where E(R) 2 R* represents a Group 15 neutral electron donor ligand and where R* is an anionic hydrocarbyl containing moiety, bonded to the Pd and having a β hydrogen with respect to the Pd center. Such compound composition exhibits latent polymerization activity in the presence of polycyclic olefins.

  钯化合物组成按照以下公式提供：[((R)3E)aPd(Q)(LB)b]p[WCA]r，其中((R)3E)是第15族电子供体配体，Q是阴离子配体，LB是路易斯碱，WCA是弱配位阴离子，a为1、2或3，b为0、1或2，a和b的总和为1、2或3，p和r各自为整数，使得分子电荷为零，或[(E(R)3)(E(R)2R*)Pd(LB)]p[WCA]r，其中E(R)2R*代表第15族中性电子供体配体，R*是与Pd键合的含有阴离子烃基的部分，并且相对于Pd中心具有β氢。这种化合物组成在多环烯烃存在时表现出潜在的聚合活性。
• Coupling of nucleophiles, vinyl compounds or CO with water, alcohols or amines to organic compounds
  申请人：Solvias AG

  公开号：EP1132361A1

  公开（公告）日：2001-09-12

  Process for the coupling of a) nucleophiles selected from the group alcohols, thioles, amines, metallised hydrocarbons, CH-acidic compounds and metal cyanides, or of b) carbon monoxide mixed with water, alcohols, ammonia, primary or secondary amines, to organic compounds selected from the group of leaving-group-containing aromatics, hetero-aromatics with a C-bonded leaving group, aromatic or hetero-aromatic methyl compounds with a leaving group bonded to the methyl group, ethylenically unsaturated organic compounds with a C-bonded leaving group, or organic allyl compounds with a leaving group in allyl position, or c) vinyl compounds with leaving-group-containing aromatics, whilst cleaving the leaving group in the presence of Pd complexes with monophospholine ligands as the catalyst, whereby variants b) and c) are carried out in the presence of an inorganic base or organic nitrogen base, the process being characterised in that the Pd complex contains secondary monophosphines with aliphatic, branched or cyclic substituents as ligands.

  耦合工艺 a) 选自醇、硫醇、胺、金属化烃、CH 酸性化合物和金属氰化物组的亲核物，或 b) 与水、醇、氨、伯胺或仲胺混合的一氧化碳，与选自以下组别的有机化合物发生偶联：含离去基团的芳香族化合物、带有 C 键离去基团的杂芳香族化合物、带有与甲基键合的离去基团的芳香族或杂芳香族甲基化合物、带有 C 键离去基团的乙烯基不饱和有机化合物或在烯丙基位置带有离去基团的有机烯丙基化合物，或 c) 含离去基团芳香族的乙烯基化合物、 在具有单磷配体的钯络合物作为催化剂存在的情况下裂解离去基团，其中变体 b) 和 c) 在无机碱或有机氮碱存在的情况下进行，该工艺的特点是钯络合物含有脂肪族、支链或环状取代基作为配体的仲单磷酸。
• SINGLE COMPONENT CATIONIC PALLADIUM PROINITIATORS FOR THE LATENT POLYMERIZATION OF CYCLOOLEFINS
  申请人：Promerus, LLC

  公开号：EP1680218A2

  公开（公告）日：2006-07-19
• METHODS FOR SUPPRESSING DEHYDROGENATION
  申请人：Elevance Renewable Sciences, Inc.

  公开号：EP2859068A1

  公开（公告）日：2015-04-15
• METHODS OF REFINING NATURAL OILS, AND METHODS OF PRODUCING FUEL COMPOSITIONS
  申请人：ELEVANCE RENEWABLE SCIENCES, INC.

  公开号：US20130331586A1

  公开（公告）日：2013-12-12

  A method for suppressing dehydrogenation includes reacting an optionally functionalized olefin reactant in a metathesis reaction to form an olefin metathesis product; and providing a dehydrogenation suppression agent in admixture with (a) the olefin metathesis product and/or the optionally functionalized olefin reactant, and (b) a metal-containing material selected from the group consisting of residual metathesis catalyst, a hydrogen transfer agent, and a combination thereof, under conditions that are sufficient to passivate at least a portion of the metal-containing material. Methods of refining natural oils and methods of producing fuel compositions are also described.