tris(trimethylene diamine)cobalt(III) perchlorate | 16786-53-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: tris(trimethylene diamine)cobalt(III) perchlorate
• 英文别名: [Co(1,3-diaminopropane)3][ClO4]3；[Co(tn)3][ClO4]3
• CAS: 16786-53-1
• 化学式: C₉H₃₀CoN₆*3ClO₄
• 分子量: 579.722
• InChiKey: BWYZBWZUUDBVHU-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  高氯酸 、 sodium tris(carbonato)cobaltate(III) trihydrate 、 1,3-丙二胺 以 not given 为溶剂， 生成 tris(trimethylene diamine)cobalt(III) perchlorate
  参考文献：
  名称：

  Determination of the structural formula of sodium tris-carbonatocobaltate(III), Na3[Co(CO3)3]·3H2O by thermogravimetry

  摘要：

  The existence of an inner sphere water in sodium tris-carbonatocobaltate(III) prepared by the Bauer and Drinkard method was confirmed by thermogravimetry, which led to its formulation as sodium aquo-tris-carbonatocobaltate(III) dihydrate, Na3[Co(H2O)(CO3)3]·2H2O. Hydrolytic study on 4-nitrophenylphosphate promoted by [Co(tn)3]3+ afforded corborating evidence for the existence of inner sphere water in the complex leading to its formulation as [Co(tn)3(H2O)]3+. Another variety of the tris-carbonato anion, [Co(NH3)6][Co(CO3)3], was prepared and subjected to thermogravimetric analysis, and the absence of inner sphere water in the compound was confirmed. The plausible existence of inner sphere water for the compounds that emanate from the synthetic routes utilizing the Bauer and Drinkard method in the crystalline phase is proposed.

  DOI：

  10.1007/s10973-009-0606-2