[Cu(N,N'-di-4-(4'-pentyloxybenzoate)salicylidene diaminoethane-2H)] | 1104346-18-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [Cu(N,N'-di-4-(4'-pentyloxybenzoate)salicylidene diaminoethane-2H)]
• CAS: 1104346-18-0
• 化学式: C₄₀H₄₂CuN₂O₈
• 分子量: 742.328
• InChiKey: PIHZWALTRQBHQI-JHRROAEHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-di-4-(4'-pentyloxybenzoate)salicylidene diaminoethane 、 copper diacetate 以 乙醇 、 二氯甲烷 为溶剂， 以70%的产率得到[Cu(N,N'-di-4-(4'-pentyloxybenzoate)salicylidene diaminoethane-2H)]
  参考文献：
  名称：

  Coordination of a mesogenic Schiff-base with MnII, CoII, NiII, CuII and ZnII: Synthesis, spectral studies and crystal structures

  摘要：

  A novel mesogenic (nematic) Schiff-base, N,N'-di-4-(4'-pentyloxybenzoate)salicylidene diaminoethane, H(2)dpbsde (abbreviated as H2L5) was synthesized and its structure studied. The Schiff-base crystallizes in the non-centrosymmetric space group Pna2(1) with Z = 4, and the mesogenic isomorphous nickel and copper complexes, [NiL5](2) and [CuL5], in the centrosymmetric space group P2(1)/c with Z = 4. The (L-5)(2)-species coordinates to the metal ions through two phenolate oxygens and two azomethine nitrogens. Both the [NiL5](2) and [CuL5] complexes involve cis-MN2O2 planes; the former complex has a low-spin distorted square-pyramidal geometry with a Ni-Ni bonding of 3.337 angstrom and the latter, a square-planar geometry. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.09.013