(η(5)-pentamethylcyclopentadienyl)(η(5)-2,4,5-tri-t-butyl-1,3-diphosphacyclopentadienyl)ruthenium(II) | 165679-62-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: (η(5)-pentamethylcyclopentadienyl)(η(5)-2,4,5-tri-t-butyl-1,3-diphosphacyclopentadienyl)ruthenium(II)
• 英文别名: (η(5)-pentamethylcyclopentadienyl)(η(5)-1,3,4-triphospha-2,5-di-tert-butylcyclopentadienyl)ruthenium
• CAS: 165679-62-9
• 化学式: C₂₀H₃₃P₃Ru
• 分子量: 467.473
• InChiKey: XHYNJSZEMPYTDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate 在 [Li(tmen)2][P₂SbC₂tBu₂]/[Li(tmen)2][P₃C₂tBu₂] 作用下， 以 乙二醇二甲醚 为溶剂， 生成 、 (η(5)-pentamethylcyclopentadienyl)(η(5)-2,4,5-tri-t-butyl-1,3-diphosphacyclopentadienyl)ruthenium(II)
  参考文献：
  名称：

  Polyhetero-ferrocenes and -ruthenocenes derived from the 1,4,2-diphosphastibolyl ring anion [P2SbC2But2]−

  摘要：

  ](η 5 3C 2Bu 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 17 18 19 与FeCl2反应只产生一种异构体，即[Fe(η5-P2SbC2But2)2](η53C2Bu2345678910111213141516171819171819。 该反应生成的产物为一种具有双铁环的二茂铁配合物，其结构为[Fe(η5-P2SbC2But2)2](η5

  DOI：

  10.1039/a700869d

文献信息

• Syntheses and Structures of Diruthenium Triple-Decker Complexes with Bridging 1,2,4-Triphospholyl and 1-Arsa-3,4-Diphospholyl Anions
  作者：Peter B. Hitchcock、Julian A. Johnson、John F. Nixon

  DOI：10.1021/om00009a048

  日期：1995.9

  Yellow-brown oils, characterized spectroscopically as [Cp*Ru(eta(5)-C-2-t-Bu(2)P(3))], 11, and [Cp*Ru(eta(5)-C-2-t-Bu(2)AsP(2))], 12, were isolated from the reaction of [Cp*Ru(CH3CN)(3)][PF6], 6, with [Li(C-2-t-Bu(2)P(3))], 2, or [Li(C-2-t-Bu(2)AsP(2))], 4, respectively. Both 11 and 12 reacted further with 6 to give the triple-decker complexes [Cp*Ru(mu-eta(5):eta(5)-C-2-t-Bu(2)P(3))RuCp*][PF6], 7, and [Cp*Ru(mu-eta(5):eta(5)-C-2-t-Bu(2)AsP(3))RuCp*][PF6], 8, in which the triphospholyl or arsadiphospholyl anions bridge two ruthenium centers. Both 7 and 8 have been characterized by single-crystal X-ray crystal structure determinations. Crystal data for C30H48F6P4Ru2, 7: M = 848.7, P2(1)2(1)2(1), a = 12.642(9) Angstrom, b = 15.151(10 Angstrom, c = 18.176(10) Angstrom, V = 3481.4 Angstrom(3), D-caled = 1.62 g cm(-3) (Z = 4) mu = 10.8 cm(-1) for Mo K alpha radiation (lambda = 0.7107 Angstrom), final R = 0.055, R(w) = 0.057, from 2716 observed reflections (3437 measured). Data for C30H48AsF6P3Ru2, 8: M = 892.7, P2(1)2(1)2(1), a = 12.650(9) Angstrom, b = 15.147(8) Angstrom, c = 18.111(10) Angstrom V = 3470.1 Angstrom(3), D-caled = 1.71. g cm(-3) (Z = 4) mu = 19.9 cm(-1) for Mo K alpha radiation (lambda = 0.7107 Angstrom), final R = 0.049, R(w) = 0.053, from 2760 observed reflections (3430 measured). Attempts to prepare mixed-metal triple-decker complexes by reacting [Fe(eta(5)-C(5)R(5))(eta(5)-C-2-t-Bu(2)P(3))] (R = H, 14a; R = Me, 14b] or [Fe(eta(5)-C(5)R(5))(eta(4)5-C-2-t-Bu(2)AsP(2))] (R = H, 15a; R = Me, 15b) with 6 were unsuccessful. Likewise, when either 14a or 15a is treated with 6 the intermediate complexes [Fe(eta(5)-C5H5)(eta(5)-C-2-t-Bu(2)P(3))RuCp*(CH3CN)(2)][PF6], 17, or [Fe(eta(5)-C5H5)(eta(5)-C-2-t-Bu(2)AsP(2))RuCp*(CH3 CN)(2)][PF6], 18, were isolated and spectroscopically characterized. When these were heated in nitromethane, a ring transfer occurred and the triple-decker species 7 or 8 was observed. Similar reactions involving 14b or 15b led directly to 7 or 8 without detection of any intermediate complexes.
• Tri-, penta-, and hexa-phospha ruthenocenes
  作者：Peter B. Hitchcock、John F. Nixon、Robson M. Matos

  DOI：10.1016/0022-328x(94)05212-t

  日期：1995.3

  Synthesis and structural studies of the ruthenium(II) 'sandwich' complexes [Ru(eta(5)-P(3)C(2)(t)Bu(2))(2)], [Ru(eta(5)-P(3)C(2)(t)Bu(2))(eta(5)-P(2)C(3)(t)Bu(3))], and [Ru(eta(5)-C(5)R(5))(eta(5)-P(3)C(2)(t)Bu(2))] (R = H, Me) are described. The results of a single crystal X-ray structural study of [Ru(eta 5-P(3)C(2)(t)Bu(2))(2)] are discussed.
• The first diphosphastibolyl complexes: synthesis and characterisation of [Ru(η⁵-C₅R₅)(η⁵-C₂Bu^t₂P₂Sb)]; R = H or Me
  作者：Matthew D. Francis、David E. Hibbs、Michael B. Hursthouse、Cameron Jones、K. M. Abdul Malik

  DOI：10.1039/cc9960001591

  日期：——

  Treatment of the novel ring anion [C(2)Bu(2)(t)P(2)Sb](-) 4 with [Ru(eta(5)-C(5)R(5))(MeCN)(3)]PF6, (R = H, Me), affords the compounds [Ru(eta(5)-C(5)R(5))(eta(5)-(C2BU2P2Sb)-P-t)] (R = H 6, Me 7), which represent the first examples of complexes derived from a diphosphastibolyl ring; the X-ray crystal structure of 7 is described.