4-((4-(dimethylamino)phenyl)diazenyl)-3-nitrobenzaldehyde oxime | 1246462-16-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 4-((4-(dimethylamino)phenyl)diazenyl)-3-nitrobenzaldehyde oxime
• CAS: 1246462-16-7
• 化学式: C₁₅H₁₅N₅O₃
• 分子量: 313.316
• InChiKey: PXAULWAUUYIBOK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  4-((4-(dimethylamino)phenyl)diazenyl)-3-nitrobenzaldehyde 在 盐酸羟胺 、 三乙胺 作用下， 以 乙醇 为溶剂， 反应 3.0h， 以79.8%的产率得到4-((4-(dimethylamino)phenyl)diazenyl)-3-nitrobenzaldehyde oxime
  参考文献：
  名称：

  Highly selective and sensitive colorimetric probes for hypochlorite anion based on azo derivatives

  摘要：

  Two oxime-based colorimetric probes for the hypochlorite anion (ClO(-)) have been rationally designed and synthesized on basis of the mechanism of intramolecular charge transfer (ICT). Upon addition of ClO(-), the probes displayed around 20 nm redshift in the absorption maximum, accompanied with the color change from orange to pink, which were attributed to the reaction of the oxime groups with ClO(-) to form aldehyde groups. The probes were highly selective for ClO(-) detection without the interference of other ions and oxidants. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2010.05.028