ytterbium acetylacetonate-5,10,15,20-tetra[para-(4-fluorobenzoyloxy)-meta-methoxy]phenylporphyrin | 443784-91-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: ytterbium acetylacetonate-5,10,15,20-tetra[para-(4-fluorobenzoyloxy)-meta-methoxy]phenylporphyrin
• CAS: 443784-91-6
• 化学式: C₈₁H₅₅F₄N₄O₁₄Yb
• 分子量: 1557.38
• InChiKey: GTIBKKPANFHIPA-KCJSGTKCSA-N

反应信息

• 作为产物：
  描述：

  ytterbium(III) acetylacetonate 、 5,10,15,20-tetra[para-(4-fluorobenzoyloxy)-meta-methoxy]phenylporphyrin 以 further solvent(s) 为溶剂， 以62%的产率得到ytterbium acetylacetonate-5,10,15,20-tetra[para-(4-fluorobenzoyloxy)-meta-methoxy]phenylporphyrin
  参考文献：
  名称：

  LANTHANIDE COMPLEXES WITH ACETYLACETONATE AND 5,10,15,20-TETRA[PARA-(4-FLUOROBENZOYLOXY)-META-METHOXY]PHENYLPORPHYRIN

  摘要：

  Lanthanide complexes of acetylacetonate and 5,10,15,20-tetra [para-(4-fluorobenzoyloxy)-meta-methoxy]phenylporphyrin having the general formula Ln[(FBOMP)(4)P](acac) (where Ln=Er, Tm, Yb; FBOMP=[para-(4-fluorobenzoyloxy)meta-methoxy]phenyl; acac=acetylacetone; P=porphyrin) have been prepared and characterized. A structure is proposed in which one 5,10,15,20-tetra[para-(4-fluorobenzoyloxy)meta-methoxy]porphyrin molecule is coordinated to a rare earth ion in a tetradentate fashion, while one acetylacetonate molecule is coordinated to the same metal ion in a bidentate fashion.

  DOI：

  10.1081/sim-120003789