11-[4-(4-cyanophenylazo)phenoxy]undecyl methacrylate | 185838-55-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 11-[4-(4-cyanophenylazo)phenoxy]undecyl methacrylate
• CAS: 185838-55-5
• 化学式: C₂₈H₃₅N₃O₃
• 分子量: 461.604
• InChiKey: VSYYBOURTGYSGN-NVQSTNCTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.98
• 重原子数：
  34.0
• 可旋转键数：
  16.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  84.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  苯酚 、 alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 、 potassium carbonate 、 sodium nitrite 作用下， 以 乙醇 、 水 为溶剂， 生成 11-[4-(4-cyanophenylazo)phenoxy]undecyl methacrylate
  参考文献：
  名称：

  Photoinduced Alignment of Nanocylinders by Supramolecular Cooperative Motions

  摘要：

  A linearly polarized laser beam was used to control nanocylinders self-assembled in an amphiphilic diblock liquid-crystalline copolymer consisting of flexible poly(ethylene oxide) as a hydrophilic block and poly(methacrylate) containing an azobenzene moiety in the side chain as a hydrophobic liquid-crystalline segment. The perfect array of poly(ethylene oxide) nanocylinders was achieved, aligned perpendicularly to the polarization direction of the actinic light by supramolecular cooperative motions between the ordered azobenzene and microphase separation. By the simple and convenient way of photocontrol, the macroscopic parallel patterning of nanocylinders can be easily obtained in an arbitrary area.

  DOI：

  10.1021/ja064148f