{trans-Pt(H)(PEt3)2(THF)}{SbF6} | 119455-71-9

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: {trans-Pt(H)(PEt3)2(THF)}{SbF6}
• 英文别名: hexafluoroantimony(1-);oxolane;platinum(1+) monohydride;triethylphosphane
• CAS: 119455-71-9
• 化学式: C₁₆H₃₉OP₂Pt*F₆Sb
• 分子量: 740.253
• InChiKey: LCCAQFNDIYBAHG-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {trans-Pt(H)(PEt3)2(THF)}{SbF6} 、 bis(3,3-dimethyl-1-butynyl)diphenylsilane 在 H₂O 作用下， 以 二氯甲烷 为溶剂， 以51%的产率得到(C₆H₅)2SiCC(CH₃)3CCHC(CH₃)3CPt(P(C₂H₅)3)2(H₂O)⁽¹⁺⁾*SbF₆^(1-)={(C₆H₅)2SiCC(CH₃)3CCHC(CH₃)3CPt(P(C₂H₅)3)2(H₂O)}SbF₆
  参考文献：
  名称：

  Transformation of Ph2Si(C.tplbond.CCMe3)2 to a 4-alkylidene-1-silacyclobut-2-enyl ligand by platinum-hydrogen addition and rearrangement reactions

  摘要：

  DOI：

  10.1021/ja00201a053

文献信息

• Transformation of O₂S(CCCMe₃)₂to an exoalkylidene thiete 1,1-dioxide ligand by Pt-H addition and rearrangement reactions
  作者：Charles M. Lukehart、Andrew T. McPhail、Donald R. Mcphail、Margret D. Owen

  DOI：10.1039/c39900000215

  日期：——

  Addition of a Pt-H bond to the CC bond of an alkynyl substituent of a dialkynylsuiphone occurs regioselectively to give an exoalkylidene thiete 1, 1-dioxide ligand following a subsequent insertion and rearrangement of the second alkynyl substituent; a proposed mechanism for the unusual formation of the heterocyclic ligand is presented.

  在随后的第二个炔基取代基的插入和重排后，将Pt-H键加到二炔基电话的炔基取代基的C C键上，是区域选择性的，从而得到外亚烷基噻吩基1，1-二氧化物配体。提出了异常配位的杂环配体的建议机制。
• Dema, Anne C.; Li, Xiaohu; Lukehart, Charles M., Organometallics, 1991, vol. 10, # 4, p. 1197 - 1200
  作者：Dema, Anne C.、Li, Xiaohu、Lukehart, Charles M.、Owen, Margret D.

  DOI：——

  日期：——
• Transformation of a trialkynylphosphine oxide to a 2-alkylidene-1,2-dihydro-3-phosphete P-oxide ligand by Pt-H addition and rearrangement reactions. Activation of molecular hydrogen by a platinum(II) complex
  作者：Charles M. Lukehart、Andrew T. McPhail、Donald R. McPhail、James B. Myers、Hitesh K. Soni

  DOI：10.1021/om00106a022

  日期：1989.4
• Transformation of a trialkynylarsine oxide to an arsacyclobutenyl ligand containing a spirocyclic arsenic center
  作者：Xiaohu Li、C. M. Lukehart、Andrew T. McPhail、Donald R. McPhail

  DOI：10.1021/om00048a002

  日期：1991.2

  The trialkynylarsine oxide (Me3CC = C)3AsO reacts with 2 equiv of [trans-Pt(H)(PEt3)2(THF)][SbF6], and subsequently with pyridine, to give a spirocyclic arsenic compound in which the arsenic atom participates in two four-membered rings. One ring is an arsacyclobutene that bears an alkylidene substituent at the 2-position.
• Reactions of di- or trialkynylphosphine and di- or trialkynylarsine oxides with a cationic platinum-hydride complex: mechanistic features
  作者：Xiaohu Li、Charles M. Lukehart、Lu Han

  DOI：10.1021/om00060a013

  日期：1992.12

  The reaction between a cationic Pt-H complex and O=P(=CMe3)3 was followed by P-31 NMR at three temperatures. Addition of the Pt-H bond to an alkynyl substituent to give a PtP-mu-alkenylidene complex is observed with subsequent formation of the expected 1,2-dihydrophosphete product. A similar reaction with O=AsPh(C=CCMe3)2 occurs with unexpected overall transfer of both alkynyl substituents from the As atom to the Pt ion, giving eventually a cationic Pt(II)(eta1-alkynyl)(eta1-alkenyl) product. The X-ray structure of this latter complex has been determined: P1BAR; Z = 2; a = 11.391 (4) angstrom, b = 16.040 (4) angstrom, c = 10.801 (1) angstrom; alpha = 100.13 (1)-degrees, beta = 100.71 (2)-degrees, gamma = 80.23 (2)0. A mechanism of formation of 1,2-dihydrophosphete or -arsete complexes involving Pt-H addition and subsequent alkynyl transmetalation is postulated.