Phosphabicycloheptan | 29310-25-6

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: Phosphabicycloheptan
• 英文别名: 1-phospha-bicyclo[2.2.1]heptane；Phosphabicyclo[2.2.1]heptane；1-phosphabicyclo[2.2.1]heptane
• CAS: 29310-25-6
• 化学式: C₆H₁₁P
• 分子量: 114.127
• InChiKey: GOJUCLZTHGBBFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• PROCESS FOR PRODUCING CARBONYL COMPOUNDS BY DEHYDROGENATION OF ALCOHOLS
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP1160245A1

  公开（公告）日：2001-12-05

  The present invention provides a method for producing a carbonyl compound by dehydrogenating an alcohol. Namely, it relates to a method for producing a carbonyl compound, which comprises dehydrogenating an alcohol in the presence of a complex compound catalyst comprising ruthenium and an organic phosphine wherein aliphatic carbons are bonded to two or more of the three bonding hands of the phosphorus atom.

  本发明提供了一种通过脱氢醇生产羰基化合物的方法。也就是说，本发明涉及一种生产羰基化合物的方法，该方法包括在由钌和有机膦组成的复合催化剂存在下对醇进行脱氢，其中脂肪族碳与磷原子三个键手中的两个或两个以上键手成键。
• Asymmetric synthesis catalyzed by transition metal complexes with rigid chiral ligands
  申请人：The Penn State Research Foundation

  公开号：US20010047113A1

  公开（公告）日：2001-11-29

  This invention is to develop novel transition metal catalysts for the practical synthesis of important chiral molecules. The invention emphasizes asymmetric catalysis based on chiral bidentate phosphine ligands with cyclic ring structures which could be used to restrict conformational flexibility of the ligands and thus the efficiency of chiral transfer can be enhanced through the ligand rigidity.

  本发明旨在开发新型过渡金属催化剂，用于重要手性分子的实际合成。本发明强调基于具有环状结构的手性双齿膦配体的不对称催化，这种结构可用于限制配体的构象灵活性，从而通过配体的刚性提高手性转移的效率。
• Method for producing carbonyl compound by dehydrogenating alcohol
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20020002289A1

  公开（公告）日：2002-01-03

  The present invention provides a method for producing a carbonyl compound by dehydrogenating an alcohol. Namely, it relates to a method for producing a carbonyl compound, which comprises dehydrogenating an alcohol in the presence of a complex compound catalyst comprising ruthenium and an organic phosphine wherein aliphatic carbons are bonded to two or more of the three bonding hands of the phosphorus atom.

  本发明提供了一种通过脱氢醇生产羰基化合物的方法。也就是说，本发明涉及一种生产羰基化合物的方法，该方法包括在由钌和有机膦组成的复合催化剂存在下对醇进行脱氢，其中脂肪族碳与磷原子三个键手中的两个或两个以上键手成键。
• ASYMMETRIC SYNTHESIS AND CATALYSIS WITH CHIRAL HETEROCYCLIC COMPOUNDS
  申请人：THE PENN STATE RESEARCH FOUNDATION

  公开号：EP1021451A1

  公开（公告）日：2000-07-26
• EP1021451A4
  申请人：——

  公开号：EP1021451A4

  公开（公告）日：2001-02-14