m-Vinylbenzoesaeure-phenylester | 38499-14-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: m-Vinylbenzoesaeure-phenylester
• 英文别名: Phenyl 3-ethenylbenzoate
• CAS: 38499-14-8
• 化学式: C₁₅H₁₂O₂
• 分子量: 224.259
• InChiKey: RXGYHQBYNSMGOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-乙烯基苯甲酰氯 、 苯酚 、 三乙胺 以70%的产率得到
  参考文献：
  名称：

  POGOSYAN G. M., XIMIYA NEPREDELNYX SOEDIN., (EREVAN), 1979, HO 1, 159-179

  摘要：

  DOI：

文献信息

• [EN] NOVEL ORGANOPOLYSILOXANE, SURFACE TREATMENT AGENT COMPRISING THE SAME, RESIN COMPOSITION COMPRISING THE SAME, AND GELATINOUS PRODUCT OR CURED PRODUCT THEREOF<br/>[FR] NOUVEL ORGANOPOLYSILOXANE, AGENT DE TRAITEMENT DE SURFACE LE COMPORTANT, COMPOSITION DE RÉSINE LE COMPORTANT ET SON PRODUIT GÉLATINEUX OU SON PRODUIT DURCI
  申请人：DOW CORNING TORAY CO LTD

  公开号：WO2015023001A1

  公开（公告）日：2015-02-19

  An organopolysiloxane represented by formula : R63Si-R5-[SiR42 O]n-Si R3(3-a)-[R2-R1]a (wherein R1 is a monovalent hydrocarbon group having a plurality of aromatic rings with 10 or more carbon atoms; R2 is a divalent hydrocarbon group which may contain a hetero atom or a direct bond to a silicon (Si) atom; each of R3 and R4 is independently a monovalent hydrocarbon group; R5 is a divalent hydrocarbon group which may contain a hetero atom, or an oxygen atom; each R6 is a group independently selected from alkyl groups, alkenyl groups, aryl groups, and alkoxy groups, n is an integer from 0 to 200; and a is an integer from 1 to 3); the use thereof as a surface treatment agent, and a resin composition comprising the organopolysiloxane and a functional filler.

  一种有机聚硅氧烷，其化学式为：R63Si-R5-[SiR42 O]n-Si R3(3-a)-[R2-R1]a（其中，R1是一种具有10个或更多碳原子的多环芳烃基的一价烃基；R2是一种二价烃基，可以包含一个杂原子或直接与硅（Si）原子结合；每个R3和R4都是独立的一价烃基；R5是一种二价烃基，可以包含一个杂原子或一个氧原子；每个R6是从烷基、烯基、芳基和烷氧基中独立选择的一组，n是从0到200的整数；a是从1到3的整数）；其用作表面处理剂，以及包括该有机聚硅氧烷和功能性填料的树脂组合物。
• CROSSLINKABLE AROMATIC RESINS HAVING PROTONIC ACID GROUPS AND ION CONDUCTIVE POLYMER MEMBRANES BINDERS AND FUEL CELLS MADE BY USING THE SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1457511A1

  公开（公告）日：2004-09-15

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C1 to C10 alkyl group directly bonded to the aromatic ring and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由直接键合在芳香环上的 C1 至 C10 烷基和羰基或碳碳双键或三键组成。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂，是优选的。
• Crosslinkable aromatic resin having protonic acid group, and ion conductive polymer membrane, binder and fuel cell using the resin
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20040191602A1

  公开（公告）日：2004-09-30

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C 1 to C 10 alkyl group directly bonded to the aromatic ring and/or an alkylene group having 1 to 3 carbon atoms in the main chain in which at least one carbon atom directly bonded to the aromatic ring bonds to hydrogen, and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由 C 1 至 C 10 烷基和/或主链上有 1 至 3 个碳原子的亚烷基，其中至少有一个直接与芳香环键合的碳原子与氢、羰基或碳碳双键或三键键合。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂是首选。
• US7345135B2
  申请人：——

  公开号：US7345135B2

  公开（公告）日：2008-03-18
• [EN] MULTIFOCAL DIFFRACTIVE SILICONE HYDROGEL CONTACT LENSES<br/>[FR] LENTILLES DE CONTACT MULTIFOCALES À DIFFRACTION EN HYDROGEL DE SILICONE
  申请人：[en]ALCON INC.

  公开号：WO2022263994A1

  公开（公告）日：2022-12-22

  The invention provides a delamination-resistant embedded silicone hydrogel contact lens having an insert that is embedded in a silicone hydrogel bulk material. The insert is made of a crosslinked polymeric material having a refractive index higher than that of the silicone hydrogel bulk material by at least 0.07 and comprises a diffractive structure disposed on one of the front and back curve surfaces of the insert for providing a diffractive power that contributes to the overall optical power of the contact lens.