Phthalic acid 1-allyl ester 2-phenyl ester | 97770-50-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: Phthalic acid 1-allyl ester 2-phenyl ester
• 英文别名: 2-O-phenyl 1-O-prop-2-enyl benzene-1,2-dicarboxylate
• CAS: 97770-50-8
• 化学式: C₁₇H₁₄O₄
• 分子量: 282.296
• InChiKey: PCOVYQKBPSKHLD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Polyurethanes, polyurethane foams and methods for their manufacture
  申请人：Imperial Sugar Company

  公开号：US10323116B2

  公开（公告）日：2019-06-18

  Polyurethane foams are described, as well as the production of such polyurethane foams by the reaction between a natural polyol, such as sucrose or a blend of mono- or disaccharides in place of the standard hydrocarbon-based polyol component, an ionic liquid or a deep eutectic solvent, a polyisocyanate and water in the presence of a suitable polyurethane forming catalyst and optionally a flame retardant, and optionally one or more components such as surfactants and/or emulsifiers. The resultant polyurethane foam can exhibit a bio-based solid content ranging from about 17% to 30%, may be formulated in a variety of foam densities for a variety of applications, and in the instance where a flame retardant has been added in an appropriate amount, exhibits a high degree of fire and burn resistance, as exhibited by the flame spread index and/or the smoke spread values.

  本文介绍了聚氨酯泡沫塑料以及聚氨酯泡沫塑料的生产方法，即在适当的聚氨酯成 形催化剂和阻燃剂以及表面活性剂和/或乳化剂等一种或多种成分存在的情况下，天然 多元醇（如蔗糖或单糖或双糖混合物）代替标准的碳氢化合物多元醇成分、离子液体 或深共晶溶剂、多异氰酸酯和水发生反应。由此产生的聚氨酯泡沫的生物基固体含量约为 17% 至 30%，可配制成各种泡沫密度，适用于各种应用，在添加适量阻燃剂的情况下，具有很高的阻燃性，如火焰蔓延指数和/或烟雾扩散值所示。
• Composition for use in flexible polyurethane foams
  申请人：Ferro Corporation

  公开号：US20040014830A1

  公开（公告）日：2004-01-22

  A plasticizer with a crosslinking/chain extending agent is incorporated into a water-blown flexible polyurethane foam formulation to provide acceptable softness, openness, and tensile strength characteristics. The class of plastisizers is selected from the group consisting of alkyl benzyl phthalates, phosphate esters and benzoates. The aromatic polyhydroxy compounds are a preferred class of crosslinking/chain extending agents, particularly dihydroxyaromatic compounds, more particularly resorcinol. Other classes of preferred crosslinking/extending agents are saccharides, alkyl glycosides, and alkylene oxide adducts of aliphatic triols. Other preferred crosslinker/extenders include epoxidized soybean oil, polymeric 1,3,5-trimethyl, 2-hydroxy-benzene, selected phenolic resins, selected low molecular weight adducts of a polyfunctional aliphatic amines, and polyoxyalkylene polyols wherein the hydroxyl number is less than about 200 and the average number of hydroxyl groups range from about 3 to about 8.

  在水发泡软质聚氨酯泡沫配方中加入一种带有交联剂/链延伸剂的增塑剂，以提供可接受的柔软度、开放性和拉伸强度特性。该类增塑剂选自邻苯二甲酸烷基苄酯、磷酸酯和苯甲酸酯组成的组。芳香族多羟基化合物是首选的一类交联剂/链延伸剂，特别是二羟芳香族化合物，尤其是间苯二酚。其他优选的交联剂/延链剂有糖类、烷基糖苷和脂肪族三醇的环氧亚烷基加合物。其他优选的交联剂/扩展剂包括环氧化大豆油、聚合 1,3,5-三甲基 2-羟基苯、精选的酚醛树脂、精选的多官能团脂肪胺低分子量加合物，以及羟基数小于约 200、羟基平均数在约 3 至约 8 之间的聚氧亚烷基多元醇。
• FLEXIBLE WATER-BLOWN POLYURETHANE FOAMS
  申请人：MONSANTO COMPANY

  公开号：EP0646154A1

  公开（公告）日：1995-04-05
• Phase change compositions and methods for selective deposition modeling
  申请人：3D SYSTEMS, INC.

  公开号：EP1033222B1

  公开（公告）日：2002-12-11
• SUGAR-BASED POLYURETHANES, METHODS FOR THEIR PREPARATION, AND METHODS OF USE THEREOF
  申请人：Imperial Sugar Company

  公开号：EP2723790A1

  公开（公告）日：2014-04-30