rhodicenium chloride | 82512-31-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: rhodicenium chloride
• 英文别名: [RhCp₂][Cl]；Cl；Chlororhodium(2+);cyclopenta-1,3-diene
• CAS: 82512-31-0
• 化学式: C₁₀H₁₀Rh*Cl
• 分子量: 268.548
• InChiKey: XDZYPWDBTQAUMS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  hexafluorophosphoric acid 、 rhodicenium chloride 以 水 为溶剂， 以140 mg的产率得到rhodicenium hexafluorophosphate
  参考文献：
  名称：

  Rhodicenium Salts: From Basic Chemistry to Polyelectrolyte and Dendritic Macromolecules

  摘要：

  A new, facile synthesis of rhodicenium chloride is described, leading to the synthesis of rhodicenium tetraarylborate, the first rhodicenium salt that is soluble in less polar solvents. This opens the route to further chemistry that was prevented by the insolubility of the formerly available rhodicenium salts. This strategy has been extended to the synthesis of water-soluble polyelectrolyte and dendritic macromolecular cobaltocenium and rhodicenium salts.

  DOI：

  10.1021/om500028e
• 作为产物：
  描述：

  [CpRuCl2](n) 、 lithium cyclopentadienide 以 四氢呋喃 为溶剂， 以62%的产率得到rhodicenium chloride
  参考文献：
  名称：

  Rhodicenium Salts: From Basic Chemistry to Polyelectrolyte and Dendritic Macromolecules

  摘要：

  A new, facile synthesis of rhodicenium chloride is described, leading to the synthesis of rhodicenium tetraarylborate, the first rhodicenium salt that is soluble in less polar solvents. This opens the route to further chemistry that was prevented by the insolubility of the formerly available rhodicenium salts. This strategy has been extended to the synthesis of water-soluble polyelectrolyte and dendritic macromolecular cobaltocenium and rhodicenium salts.

  DOI：

  10.1021/om500028e