Production of hydrated metal ions by fast ion or atom beam sputtering. Collision-induced dissociation and successive hydration energies of gaseous copper+ with 1-4 water molecules
作者:Thomas F. Magnera、Donald E. David、Dusan Stulik、Robert G. Orth、Harry T. Jonkman、Josef Michl
DOI:10.1021/ja00196a003
日期:1989.7
atoms or ions produces copious amounts of clusterions, among which M+(H2O)n and/or M+OH(H2O)n frequently dominate. Variable-energy collision-induceddissociation of these ions in a triple quadrupole mass spectrometer yields the successive gas-phase solvation energies. Several known hydration and bond energies have been reproduced, and the first and second hydration energies of the Cu+ ion have been