dichloro[(S,R)-1-diphenylphosphino-2-(ethylsulfanylmethyl)ferrocene]palladium(II) | 1030312-15-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: dichloro[(S,R)-1-diphenylphosphino-2-(ethylsulfanylmethyl)ferrocene]palladium(II)
• 英文别名: cyclopenta-1,3-diene;[2-(ethylsulfanylmethyl)cyclopenta-2,4-dien-1-yl]-diphenylphosphane;iron(2+);palladium(2+);dichloride
• CAS: 1030312-15-2
• 化学式: C₂₅H₂₅Cl₂FePPdS
• 分子量: 621.686
• InChiKey: DWDQKZSEOFNATK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.17
• 重原子数：
  31
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 2-diphenylphosphino-1-(ethylthiomethyl)ferrocene 以 二氯甲烷 为溶剂， 以81%的产率得到dichloro[(S,R)-1-diphenylphosphino-2-(ethylsulfanylmethyl)ferrocene]palladium(II)
  参考文献：
  名称：

  Palladium and platinum complexes with planar chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups

  摘要：

  Three palladium(II) complexes and four platinum(II) complexes having general formula CpFe{1,2-C(5)H(3)(PPh(2))(CH(2)SR)}MCl(2) (M = Pd, R = Ph, Et and tBu; M = Pt, R = Ph, Et, tBu and Cy) have been synthesized by reaction of the corresponding CpFe{1,2-C(5)H(3)(PPh(2))(CH(2)SR)} ligands with PdCl(2)(CH(3)CN)(2) or PtCl(2)(CH(3)CN)(2). These complexes have been fully characterized in solution and in solid state. In all cases, monomeric square planar complexes were obtained as pure diastereoisomers. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.08.021

文献信息

• Dichlorido[(<i>S</i>,<i>R</i>_S)-1-diphenylphosphino-2-(ethylsulfanylmethyl)ferrocene]palladium(II)
  作者：Lisa Diab、Jean-Claude Daran、Maryse Gouygou、Eric Manoury、Martine Urrutigoïty

  DOI：10.1107/s0108270107052742

  日期：2007.12.15

  The reaction of enantiomerically pure planar chiral ferrocene phosphine thioether with bis(acetonitrile)dichloridopalladium yields the title square-planar mononuclear palladium complex as an enantiomerically pure single diastereoisomer, [PdFe(C5H5)(C20H20PS)Cl-2]. The planar chirality of the ligand is retained in the complex and fully controls the central chirality on the S atom. The absolute configuration, viz. S for the planar chirality and R for the S atom, is unequivocally determined by refinement of the Flack parameter.