4-Phenoxy-3',4'-diamino-diphenyloxid | 24500-92-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-Phenoxy-3',4'-diamino-diphenyloxid
• 英文别名: Phenyl 4-(3,4-diaminophenoxy)benzoate
• CAS: 24500-92-3
• 化学式: C₁₉H₁₆N₂O₃
• 分子量: 320.348
• InChiKey: SYDAXZXEQCVJIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.6
• 氢给体数：
  2
• 氢受体数：
  5

文献信息

• Production of high molecular weight polybenzimidazoles
  申请人：CELANESE CORPORATION

  公开号：EP0115944A2

  公开（公告）日：1984-08-15

  This invention provides a two-stage melt polymerisation process for the production of an improved type of high molecular weight polybenzimidazole, which involves the use of an arylphosphonic acid or arylphosphonic acid polymerisation catalyst. The process provides poly-2,2'-(m-phenylene)5,5'-bi- benzimidazole of improved colour and plugging value, and is further characterised by an inherent viscosity of at least about 0.7 dl/g, and a weight average molecular weight of at least about 100,000.

  本发明提供了一种生产改良型高分子量聚苯并咪唑的两阶段熔融聚合工艺，该工艺涉及芳基膦酸或芳基膦酸聚合催化剂的使用。 该工艺提供的聚-2,2'-（间苯二酚）5,5'-联苯并咪唑具有更好的颜色和堵塞值，其进一步特征是固有粘度至少约为 0.7 dl/g，重量平均分子量至少约为 100,000 。
• Membranes prepared from blends of polybenzimidazole with polyarylates
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0354040A2

  公开（公告）日：1990-02-07

  This invention discloses novel membranes comprised of a Send of polyarylate and polybenzimidazole polymers. A membrane prepared from the blend of polybenzimidazole and polyarylate polymers exhibits enhanced properties over membranes prepared solely from either a polyarylate or a polybenzimidazole polymer. The addition of the polyarylate to the polybenzimidazole membrane allows the composition to be more thermally processable and less susceptible to moisture. The presence of the polybenzimidazole renders the polyarylate less reactive to solvents and increases its thermal stability. In addition, it has been surprisingly found that membranes prepared from the polybenzimidazole polyarylate blends show high regeneration capacity while retaining good flux ranges. The membranes prepared by this process exhibit good separation characteristics and provide an improved membrane with enhanced qualities over prior art membranes.

  本发明公开了由聚芳酸酯和聚苯并咪唑聚合物组成的新型膜。由聚苯并咪唑和聚芳酸酯聚合物混合物制备的膜与仅由聚芳酸酯或聚苯并咪唑聚合物制备的膜相比，具有更强的性能。在聚苯并咪唑膜中加入聚芳酸酯，可使组合物更易于热加工，且不易受潮。聚苯并咪唑的存在降低了聚芳酸酯对溶剂的反应性，提高了其热稳定性。此外，我们还惊喜地发现，用聚苯并咪唑聚芳酸酯混合物制备的膜具有很高的再生能力，同时还能保持良好的通量范围。通过该工艺制备的膜具有良好的分离特性，与现有技术的膜相比，其质量得到了提高。
• Proton conducting polymer membrane comprising phoshphonic acid groups containing polyazoles and the use thereof in fuel cells
  申请人：Uensal Oemer

  公开号：US20060008690A1

  公开（公告）日：2006-01-12

  The present invention relates to proton-conducting polymer membranes which comprise polyazoles containing phosphonic acid groups and are obtainable by a process comprising the steps A) mixing of one or more aromatic and/or heteroaromatic tetraamino compounds with one or more aromatic and/or heteroaromatic carboxylic acids or derivatives thereof which contain at least two acid groups per carboxylic acid monomer, with at least part of the tetraamino compounds and/or the carboxylic acids comprising at least one phosphonic acid group, or mixing of one or more aromatic and/or heteroaromatic diaminocarboxylic acids, of which at least part comprises phosphonic acid groups, in polyphosphoric acid to form a solution and/or dispersion, B) heating of the solution and/or dispersion obtainable according to step A) under inert gas at temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting.

  本发明涉及质子传导聚合物膜，该膜由含有膦酸基团的聚唑组成，可通过以下工艺获得 A) 将一种或多种芳香族和/或杂芳香族四氨基化合物与一种或多种芳香族和/或杂芳香族羧酸或其衍生物（每个羧酸单体至少含有两个酸基）混合、四氨基化合物和/或羧酸中至少有一部分含有至少一个膦酸基，或将一种或多种芳香族和/或杂芳族二氨基羧酸（其中至少有一部分含有膦酸基）混入多磷酸中，形成溶液和/或分散液， B) 在惰性气体中加热根据步骤 A) 得到的溶液和/或分散液，温度最高可达 350° C.C) 将步骤 A) 和/或 B) 中的混合物涂抹在支撑物上，形成一层膜； D) 处理步骤 C) 中形成的膜，直至其具有自支撑性。
• Proton-conducting polymer membrane that contains polyazoles and is coated with a catalyst layer, and application thereof in fuel cells
  申请人：Baurmeister Jochen

  公开号：US20060079392A1

  公开（公告）日：2006-04-13

  The present invention relates to a proton-conducting polymer membrane which comprises polyazoles and is coated with a catalyst layer and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture obtained according to step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, E) application of at least one catalyst-containing coating to the membrane formed in step C) and/or in step D).

  本发明涉及一种质子传导聚合物膜，该膜由多唑组成并涂有催化剂层，可通过以下步骤获得 A) 根据步骤 B)制备一种混合物，该混合物包括聚磷酸、至少一种多唑（聚合物 A）和/或一种或多种适合在热作用下形成多唑的化合物；B) 在惰性气体下将根据步骤 A)获得的混合物加热至最高 400 摄氏度、C）将根据步骤 A）和/或 B）获得的混合物涂敷在支撑物上，D）处理步骤 C）中形成的膜，直至其具有自支撑性，E）在步骤 C）和/或步骤 D）中形成的膜上涂敷至少一种含催化剂的涂层。
• Proton-conducting polymer membrane comprising sulfonic acid-containing polyazoles, and use thereof in fuel cells
  申请人：Uensal Oemer

  公开号：US20060183012A1

  公开（公告）日：2006-08-17

  The present invention relates to proton-conducting polymer membranes which comprise polyazoles containing sulfonic acid groups and is obtainable by a process comprising the steps A) mixing of one or more aromatic and/or heteroaromatic tetraamino compounds with one or more aromatic and/or heteroaromatic carboxylic acids or derivatives thereof which contain at least two acid groups per carboxylic acid monomer, with at least part of the tetraamino compounds and/or the carboxylic acids comprising at least one sulfonic acid group, or mixing of one or more aromatic and/or heteroaromatic diaminocarboxylic acids, of which at least part comprises sulfonic acid groups, in polyphosphoric acid to form a solution and/or dispersion, B) heating of the solution and/or dispersion obtainable according to step A) under inert gas to temperatures of up to 350 ° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane from the step C) until it is self-supporting.

  本发明涉及质子传导聚合物膜，该膜由含有磺酸基团的聚唑组成，可通过以下步骤获得 A) 将一种或多种芳香族和/或杂芳香族四氨基化合物与一种或多种芳香族和/或杂芳香族羧酸或其衍生物（每个羧酸单体至少含有两个酸基）混合、至少部分四氨基化合物和/或羧酸含有至少一个磺酸基团，或将一种或多种芳香族和/或杂芳香族二氨基羧酸（其中至少部分含有磺酸基团）混入多磷酸中，形成溶液和/或分散液、 B) 在惰性气体中加热根据步骤 A）得到的溶液和/或分散液，温度最高可达 350 C) 使用步骤 A) 和/或 B) 中的混合物在支撑物上形成一层膜， D) 对步骤 C) 中的膜进行处理，直至其具有自支撑性。