bis[(E)-4-(dodecyloxy)phenyl 4-(4-(8-hydroxyoctyloxy)-2-hydroxybenzylideneamino)benzoate]copper | 1429518-20-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: bis[(E)-4-(dodecyloxy)phenyl 4-(4-(8-hydroxyoctyloxy)-2-hydroxybenzylideneamino)benzoate]copper
• CAS: 1429518-20-6
• 化学式: C₈₀H₁₀₈CuN₂O₁₂
• 分子量: 1353.29
• InChiKey: NTHQMUJNCKIBFF-KWQFBCBVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (E)-4-(dodecyloxy)phenyl 4-(4-(8-hydroxyoctyloxy)-2-hydroxybenzylideneamino)benzoate 、 copper diacetate 以 甲醇 为溶剂， 反应 5.0h， 以83%的产率得到bis[(E)-4-(dodecyloxy)phenyl 4-(4-(8-hydroxyoctyloxy)-2-hydroxybenzylideneamino)benzoate]copper
  参考文献：
  名称：

  Novel macro metallomesogens derived from simple dihydroxy benzenes

  摘要：

  A series of tetradentate Schiff base metallomesogenic diols and their model compounds were synthesized from two simple dihydroxy benzenes. The metallomesogenic diol was constructed from three ring containing mesogen linked through ester and azomethine with terminal hydroxy group. This upon complexation with copper(II) formed metallomesogenic diol with varing terminal chain length. The related model metallomesogenic compounds were also synthesized with varying chain length with terminal methyl group and compared the properties with metallomesogenic diols. Extensive characterization of all metallomesogenic compounds and intermediates were carried out by FT-IR, H-1 & C-13 NMR, EPR, VSM, Mass (EI and FAB) and UV-Vis spectroscopy. Hot stage polarizing microscope, Differential scanning calorimetry was used to ensure the phase characteristics such as nature of phase, melting and clearing temperatures and phase range. The appearance of enantiotropic smectic A phases indicated high molecular polarizability of the core due to the metal ion. The role of copper(II) ion on mesogens were discussed. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.12.001