sulfur(II) peroxide | 164034-62-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: sulfur(II) peroxide
• 英文别名: sulfur superoxide；Oxo(sulfido)oxidanium
• CAS: 164034-62-2
• 化学式: O₂S
• 分子量: 64.0648
• InChiKey: CHHSNGKURKDPNH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  19.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  羰基硫 在 O₂ 作用下， 生成 sulfur(II) peroxide
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.3, 4.1, page 339 - 340

  摘要：

  DOI：

文献信息

• McGarvey, J. J.; McGrath, W. D., Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1964, vol. 278, p. 490 - 504
  作者：McGarvey, J. J.、McGrath, W. D.

  DOI：——

  日期：——
• Levy, A.; Merryman, E. L., Environmental science and technology, 1969, vol. 3, p. 63 - 68
  作者：Levy, A.、Merryman, E. L.

  DOI：——

  日期：——
• Ultraviolet Absorption Spectra and the Chemical Mechanism of CS₂–O₂Explosions
  作者：Albert L. Myerson、Francis R. Taylor、Philip L. Hanst

  DOI：10.1063/1.1743513

  日期：1957.5

  Ultraviolet absorption spectra have been obtained at various times during and after homogeneous explosions of carbon disulfide-oxygen mixtures thermally initiated at temperatures of 190 to 300°C. This has been accomplished by triggering a flash source of continuum by means of the early chemiluminescence of the explosion. These photographically recorded spectra show the presence, and the absorption intensity as a function of time, of CS, SO, SO2, S2O2, S2, CS2 and a species which absorbs in a continuum, to which has been assigned the structure of a sulfur superoxide, SOO. Numerous conclusions have been reached from these data concerning the elementary chemical reactions that are involved in these experiments. A direct bimolecular reaction is postulated for the initiation process which produces the superoxide, and eventually free radicals. In the very early stages of the explosion, propagation proceeds via a slowly branching primary chain which involves an attack on the reactants by sulfur and oxygen atoms. As the branching reaction proceeds and the temperature increases, the mechanism undergoes a number of changes including an increase in the importance of a nonfree radical, bimolecular process. The explosion is especially interesting in that one of the final products, sulfur dioxide, does not appear in more than minor concentrations, almost characteristic of an intermediate, until the explosion is over. This is explained in terms of the reactions postulated.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 1.3.9.1.3.2.2, page 231 - 233
  作者：

  DOI：——

  日期：——
• Sorgo, M. de; Yarwood, A. J.; Strauss, O. P., Canadian Journal of Chemistry, 1965, vol. 43, p. 1886 - 1891
  作者：Sorgo, M. de、Yarwood, A. J.、Strauss, O. P.、Gunning, H. E.

  DOI：——

  日期：——