hexaaquavanadium(II) sulfate | 22364-10-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: hexaaquavanadium(II) sulfate
• 英文别名: Vanadium(2+);sulfate;hexahydrate
• CAS: 22364-10-9
• 化学式: H₁₂O₆V*O₄S
• 分子量: 255.097
• InChiKey: LRLWNWIKXRXQMV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  hexaaquavanadium(II) sulfate 在 ethylenediamine 作用下， 以 水 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Preparation of anhydrous vanadium(II) sulfate compounds from aqueous solutions: the synthesis and characterization of [V(en)3]SO4, V(bpy)2SO4 and V(py)4SO4

  摘要：

  An easy way to prepare anhydrous vanadium(II) compounds by reaction of aqueous solutions of [V(H2O)(6)]SO4 with neutral amines is described as well as the X-ray crystal structure determinations of [V(en)(3)]SO4 . CH3OH (I) and V(bpy)(2)SO4 (II). The air-sensitive compound I crystallizes in the trigonal space group P (1) over bar 1c with a=9.009(3), c=9.570(2) Angstrom, V=672.7(3) Angstrom(3) and Z=2. II crystallizes in the monoclinic space group I2/a with a=11.957(2), b=12.071(2), c=14.614(1) Angstrom, beta=101.97(1)degrees, V=2063(1) Angstrom(3) and Z=4.

  DOI：

  10.1016/0020-1693(94)04222-h
• 作为产物：
  描述：

  硫酸氧钒水合物 在 H₂SO₄ 、 H₂O 作用下， 以 硫酸 为溶剂， 以85%的产率得到hexaaquavanadium(II) sulfate
  参考文献：
  名称：

  Cotton, F. Albert; Falvello, Larry R.; Llusar, Rosa, Inorganic Chemistry, 1986, vol. 25, # 19, p. 3423 - 3428

  摘要：

  DOI：

文献信息

• Synthesis, Structure, and Magnetic Ordering of Layered (2-D) V-Based Tris(oxalato)metalates
  作者：Kil Sik Min、Arnold L. Rhinegold、Joel S. Miller

  DOI：10.1021/ic051373+

  日期：2005.11.1

  indicating an S = 1 ground state. 2 exhibits intralayer ferromagnetic coupling below 20 K, but does not magnetically order above 2 K, and 3 shows a strong antiferromagnetic interaction between V(II), S = 3/2 and Cr(III), S = 3/2 ions (theta = -116 K) within the 2-D layers. 4 and 4a magnetically order as ferrimagnets at T(c)'s, taken as the onset of magnetization, of 11 and 30 K, respectively. The 2 K

  K 3 [M（III）（ox）3] .3H 2 O的反应[M ＝ V（1），Cr； [M + H] +。ox =草酸盐]，Mn（II）/ V（II）和[N（n-Bu）4] Br在水中导致分离出基于2-D V的配位聚合物[[N（n-Bu） 4] [Mn（II）V（III）（ox）3]] n（2），[[N（n-Bu）4] [V（II）Cr（III）（ox）3]] n（3 ），[[N（n-Bu）4] [V（II）V（III）（ox）3]] n（4）和形成4的中间体，[[N（n-Bu）4 ] [V（II）V（III）（ox）3（H2O）2]] n.2.5H2O（4a），而一维[V（II）（ox）（H2O）2] n（5）为通过在水中使用Na2ox和[V（OH2）6] SO4获得。1-5的结构已经通过单晶和/或粉末X射线晶体学研究。在1中，V（III）与三个草酸盐双阴离子配位，近似为D3对称的，扭曲的八面体八面体。1是顺磁性的[在300
• Cotton, F. Albert; Daniels, Lee M.; Murillo, Carlos A., Inorganic Chemistry, 1993, vol. 32, # 22, p. 4861 - 4867
  作者：Cotton, F. Albert、Daniels, Lee M.、Murillo, Carlos A.、Quesada, Jaime F.

  DOI：——

  日期：——
• Preparation of vanadium(II) compounds. Structures of a carboxylato and a 3-pyridinesulphonate compound
  作者：F.Albert Cotton、Lee M. Daniels、Mavis L. Montero、Carlos A. Murillo

  DOI：10.1016/s0277-5387(00)83634-7

  日期：1992.1

  Reactions of aqueous vanadium(II) sulphate with pyridine-2-carboxylate (and other carboxylic acids) and 3-pyridinesulphonate (pySO3) salts have been investigated, as well as the reaction of the products with pyridine. Two of the products have been structurally characterized by X-ray crystallography. An aquo carboxylato compound, [V(Pic)2(H2O)2] . 2H2O (I) (Pic = anion of picolinic acid), crystallizes in the monoclinic space group P2(1)/n with a = 9.930(2), b = 5.169(1), c = 14.543(2) angstrom, beta = 90.35(2)-degrees, V = 746.1(2) angstrom3 and Z = 2. Extensive hydrogen bonding in the structure provides sufficient protection to the metal centre to make the crystals relatively stable in air. The pyridine adduct V(pySO3)2(py)4 (II) possesses a molecular structure and crystallizes in the monoclinic space group C2/c with a = 17.033(4), b = 11.218(4), c = 17.396(4) angstrom, beta = 110.05(2)-degrees, V = 3122(2) angstrom3 and Z = 4. Both compounds exemplify the facile formation of bonds between vanadium(II) and nitrogen-containing ligands.
• Cotton, F. Albert; Falvello, Larry R.; Llusar, Rosa, Inorganic Chemistry, 1986, vol. 25, # 19, p. 3423 - 3428
  作者：Cotton, F. Albert、Falvello, Larry R.、Llusar, Rosa、Libby, Eduardo、Murillo, Carlos A.、Schwotzer, Willi

  DOI：——

  日期：——
• Preparation of anhydrous vanadium(II) sulfate compounds from aqueous solutions: the synthesis and characterization of [V(en)3]SO4, V(bpy)2SO4 and V(py)4SO4
  作者：Lee M. Daniels、Carlos A. Murillo、Kattia G. Rodríguez

  DOI：10.1016/0020-1693(94)04222-h

  日期：1995.2

  An easy way to prepare anhydrous vanadium(II) compounds by reaction of aqueous solutions of [V(H2O)(6)]SO4 with neutral amines is described as well as the X-ray crystal structure determinations of [V(en)(3)]SO4 . CH3OH (I) and V(bpy)(2)SO4 (II). The air-sensitive compound I crystallizes in the trigonal space group P (1) over bar 1c with a=9.009(3), c=9.570(2) Angstrom, V=672.7(3) Angstrom(3) and Z=2. II crystallizes in the monoclinic space group I2/a with a=11.957(2), b=12.071(2), c=14.614(1) Angstrom, beta=101.97(1)degrees, V=2063(1) Angstrom(3) and Z=4.