The tin sulfates Sn(SO<sub>4</sub>)<sub>2</sub> and Sn2(SO4)3: crystal structures, optical and thermal properties
作者:Matthias Hämmer、Philip Netzsch、Steffen Klenner、Kai Neuschulz、Mona Struckmann、Mathias S. Wickleder、Michael Daub、Harald Hillebrecht、Rainer Pöttgen、Henning A. Höppe
DOI:10.1039/d1dt02189c
日期:——
We report the crystal structures of two tin(IV) sulfate polymorphs Sn(SO4)2-I (P21/c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47(6) pm, β = 91.991(2)°, 4617 independent reflections, 104 refined parameters, wR2 = 0.096) and Sn(SO4)2-II (P21/n (no. 14), a = 753.90(3), b = 802.39(3), c = 914.47(3) pm, β = 92.496(2)°, 3970 independent reflections, 101 refined parameters, wR2 = 0.033). Moreover
我们报告了两种硫酸锡 ( IV ) 多晶型物Sn(SO 4 ) 2 -I ( P 2 1 / c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47 ) 的晶体结构(6) pm, β = 91.991(2)°, 4617 个独立反射, 104 个细化参数, w R 2 = 0.096) 和Sn(SO 4 ) 2 -II ( P 2 1 / n (no. 14), a = 753.90(3), b = 802.39(3), c= 914.47(3) pm, β = 92.496(2)°, 3970 个独立反射, 101 个改进参数, w R 2 = 0.033)。此外,第一个杂价硫酸锡Sn 2 (SO 4 ) 3被报道采用空间群P (no. 2) ( a = 483.78(9), b = 809.9(2), c = 1210.7(2) pm