isoprene δ-sultone | 64931-17-5

分子结构分类

有机化合物 - 有机杂环化合物 - 氧硫杂环己烯

中文名称

——

中文别名

——

英文名称

isoprene δ-sultone

英文别名

sultone；4-methyl-3,6-dihydro-[1,2]oxathiine 2,2-dioxide；4-Methyl-3,6-dihydro-2H-1,2lambda~6~-oxathiine-2,2-dione；4-methyl-3,6-dihydrooxathiine 2,2-dioxide

CAS

64931-17-5

化学式

C₅H₈O₃S

mdl

——

分子量

148.183

InChiKey

MDDWXIWOHONASS-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

物化性质

熔点：

35.5-36 °C
沸点：

304.2±31.0 °C(Predicted)
密度：

1.284±0.06 g/cm3(Predicted)

计算性质

辛醇/水分配系数(LogP)：

-0.2
重原子数：

9
可旋转键数：

0
环数：

1.0
sp3杂化的碳原子比例：

0.6
拓扑面积：

51.8
氢给体数：

0
氢受体数：

3

反应信息

作为反应物：

描述：

isoprene δ-sultone 在间氯过氧苯甲酸作用下，以二氯甲烷为溶剂，反应 66.0h，以68%的产率得到

参考文献：

名称：

Alkoxide-Directed Hydride Addition to α,β-Unsaturated Sultones

摘要：

Seven- and eight-membered beta,y-unsaturated sultones were readily prepared by ring closing metathesis. Epoxidation of these sultones and of an analogous six-membered sultone furnished the corresponding beta,gamma-epoxy sultones efficiently. Treatment of these epoxides with a suitable base gave alpha,beta-unsaturated gamma-hydroxy sultones in high yields. Reduction of both the alpha,beta-unsaturated sultones and the epoxy sultones by Red-Al is likely to proceed in a hydroxyl-directed fashion via a mixed aluminate as the reactive intermediate.

DOI：

10.3987/com-15-s(t)64
作为产物：

描述：

天然橡胶生成 isoprene δ-sultone

参考文献：

名称：

POPKOVA, T. V.;SHASTIN, A. V.;BALENKOVA, E. S., ZH. ORGAN. XIMII, 24,(1988) N 6, 1160-1165

摘要：

DOI：

点击查看最新优质反应信息

文献信息

Moiseenkov, A. M.; Zaks, I. M.; El'yanov, B. S., Journal of general chemistry of the USSR, 1983, vol. 53, # 6, p. 1125 - 1126

作者：Moiseenkov, A. M.、Zaks, I. M.、El'yanov, B. S.

DOI：——

日期：——
Synthesis of cis-1,4-bifunctional derivatives of an isoprene ?-sultone

作者：E. V. Polunin、A. M. Moiseenkov、A. V. Semenovskii

DOI：10.1007/bf00950299

日期：1981.6
Synthesis and properties of sulfoalkenyl amides

作者：I. M. Zaks、B. S. �l'ynov、V. M. Zhulin、A. M. Moiseenkov

DOI：10.1007/bf01141714

日期：1984.5
Synthesis and some properties of ?,?-unsaturated ?-sultones

作者：A. V. Semenovskii、E. V. Polunin、I. M. Zaks、A. M. Moiseenkov

DOI：10.1007/bf00947393

日期：1979.6
An easily accessible cisoid isoprenoid synthon

作者：Alexander W. Moiseenkov、Evgeni V. Polunin、Alexei V. Semenovsky

DOI：10.1016/s0040-4039(01)86703-4

日期：1979.1

同类化合物

6-乙氧基-2-甲基-5,6-二氢-1,4-氧硫杂环己二烯-3-羧酸 5,6-二氢-1,4-氧硫杂环己二烯-2-羧酸 5,6,7,8-四氢-4,7-二甲基-1,2-苯并氧硫杂环己二烯 2,2-二氧化物 2-甲基-5,6-二氢-1,4-氧硫杂环己二烯-3-甲酸 2-甲基-1,4-氧硫杂环己二烯-3-羧酸 1-(6-乙氧基-2-甲基-4-氧代-5,6-二氢-1,4-氧硫杂环己二烯-3-基)乙酮 1,4-苯并氧硫杂环己二烯4,4-二氧化物 1,4-氧硫杂环己二烯 1,4-噁噻英,2,3-二氢-5,6-二甲基- 1,2-苯并噁噻英,3,4-二氢- 1,2-氧硫杂环己二烯 methyl 6-chlorosulfonyl-3-methyl-1,2-benzoxathiin 2,2-dioxide ethyl benzo[e][1,2]oxathiine-3-carboxylate 2,2-dioxide N,N,N',N'-tetramethyl-N''-[2,2,2-trichloro-1-(5',6'-dihydro-2'-methyl-1',4'-oxathiin-3'-carboxamido)ethyl]phosphoric triamide 4-tert-butyl-1-(2,2-dioxido-1,2-benzoxathiin-6-yl)-1H-1,2,3-triazole 2-amino-4a,5,6,7,8,8a-hexahydrobenzo[b][1,4]oxathiine-3-carbonitrile 2,3-dihydro-2-methyl-2,6-diphenyl-1,4-oxathiin 2-[1-(2,2-dioxido-1,2-benzoxathiin-6-yl)-1H-1,2,3-triazol-4-yl]propan-2-ol 5,6-dihydro-[1,2]oxathiine 2,2-dioxide (+/-)-(2R,3R)-3-[(5-acetyl-6-methyl-2-prop-2-enyloxy-2H,3H-1,4-oxathiin-3-yl)methylthio]pentane-2,4-dione 2-propyl-3-(chloroethyl)-5,6-dihydro-1,4-oxathiin 3-(2-chlorobutyl)-5,6-dihydro-2-methyl-1,4-oxathiin 3-(2-chloroethyl)-5,6-dihydro-2-methyl-1,4-oxathiin 1-<5,6-dihydro-2-methyl-6-N-(2'-oxo-2',3',4',5'-tetrahydropyrrolo)-1,4-oxathiin-3-yl>ethanone 3-(2-chloroethyl)-5,6-dihydro-1,4-oxathiin 2-Butanone, 4-(4-hydroxy-2,2-dioxido-1,2-benzoxathiin-3-yl)-4-phenyl- Phosphorodithioic acid, S-2,3-dihydro-1,4-oxathiinyl O,O-dimethyl ester 4,7-Dimethyl-1,2,5,6,7,8-hexahydro-1-oxa-2-thianaphthalene 2,2-dioxide 4,5,6,7,8,9-hexahydro-1H-cyclohept[d][1,2]oxathiin-3-oxide 6,8-dichloro-1,2-benzoxathiine 2,2-dioxide 6-Morpholin-4-yl-2-phenyl-4,5,6,7-tetrahydro-9-oxa-1,8-dithia-3-aza-cyclopenta[a]naphthalene 8,8-dioxide 2-Phenyl-6-piperidin-1-yl-4,5,6,7-tetrahydro-9-oxa-1,8-dithia-3-aza-cyclopenta[a]naphthalene 8,8-dioxide ocimene sultone N,N-diisopropyl-3,4,5,6-tetrahydro-8-phenyl-1,2-oxathiino<5,6-g>benzothiazol-4-amine 2,2-dioxide N,N-dimethyl-3,4,5,6-tetrahydro-8-phenyl-1,2-oxathiino<5,6-g>benzothiazol-4-amine 2,2-dioxide 1,4-dimethyl-5,6,7,8-tetrahydro-benz[d][1,2]oxathiin-3,3-dioxide 2,2-dioxido-1,2-benzoxathiin-6-yl methanesulfonate (5,6-Dihydro-[1,4]oxathiin-2-yl)-acetic acid methyl ester acetic acid 2,2-dioxo-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester methanesulfonic acid 2,2-dioxo-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester acetic acid 2,2-dioxo-3,4-dihydro-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester methanesulfonic acid 2,2-dioxo-3,4-dihydro-2H-2λ⁶-benzo[e][1,2]oxathiin-7-yl ester ethyl 5,6-dihydro-2-trifluoromethyl-1,4-oxathiin-3-carboxylate 6-Phenyl-1,4-oxathiin-2-one 4-cyclopropyl-1-(2,2-dioxido-1,2-benzoxathiin-6-yl)-1H-1,2,3-triazole 4-(N,N-Diethylamino)-3,4,10,11-tetrahydro-5H-benzo-cyclohepta-1,2-oxathiin-2,2-dioxid (2,2-Dioxo-2,3,4,5,6,7-hexahydro-1-oxa-2λ⁶-thia-dibenzo[a,c]cyclohepten-4-yl)-diethyl-amine 6-methyl-4-pyrrolidin-1-yl-3,4,5,6,7,8-hexahydro-[1,2]oxathiino[5,6-c]pyridine 2,2-dioxide 6-methyl-4-piperidin-1-yl-3,4,5,6,7,8-hexahydro-[1,2]oxathiino[5,6-c]pyridine 2,2-dioxide 1-(2,2-Dioxo-6-phenyl-3,4-dihydro-2H-2λ⁶-[1,2]oxathiin-4-yl)-piperidine