phosphoric acid monophenyl ester; diammonium salt

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphoric acid monophenyl ester; diammonium salt
• 英文别名: Phosphorsaeure-monophenylester; Diammonium-Salz；Azane;phenyl dihydrogen phosphate
• 化学式: C₆H₇O₄P*2H₃N
• 分子量: 208.154
• InChiKey: DVYMPLMNUSZQID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.32
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  67.8
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  phosphoric acid monophenyl ester; diammonium salt 在 三氧化硫 、 N,N-二甲基甲酰胺 作用下， 生成 Phenyl-phosphosulfat
  参考文献：
  名称：

  The Syntheses and Hydrolyses ofp-Substituted Phenyl Phosphosulfates

  摘要：

  DOI：

  10.1246/bcsj.44.1139
• 作为产物：
  描述：

  diammonium salt of phenyl phosphatosulfate 在 buffer reagents of HClO₄-n-Bu₄N⁺ClO₄^- 、 水 、 magnesium 作用下， 以 乙腈 为溶剂， 生成 phosphoric acid monophenyl ester; diammonium salt
  参考文献：
  名称：

  磷酸盐。金属离子对乙腈-水混合溶剂中磷酸苯酯酸催化水解的影响

  摘要：

  已发现硫酸苯酯 (PPS) 的酸催化水解速率高度依赖于乙腈 - 水混合溶剂中的水含量。观察到显着的速率加速，最大速率接近 1:1 的 PPS 和金属离子比率，并且溶剂具有低水含量。在这种情况下，观察到 P-O-S 键的断裂位点主要是 S-O 键。

  DOI：

  10.1246/bcsj.55.1097

文献信息

• Phosphoryl transfer from phenyl and 4-nitrophenyl phosphates in aprotic and protic solvents
  作者：Fausto Ramirez、James F. Marecek

  DOI：10.1016/0040-4020(80)80159-1

  日期：1980.1

  The behavior of 4-nitrophenyl dihydrogen phosphate, ArOPO3H2, and of its tetra-n-butylammonium and tetramethylammonium salts, ArOPO3H−R4N+, ArOPO32−2(R4N+), was studied in aprotic solvents, in the absence and in the presence of increasing amounts of alcohols or water. The reactions were investigated in the absence of amines, and in the presence of hindered and unhindered amines, diisopropylethylamine

  研究了4-硝基苯基磷酸二氢盐ArOPO 3 H 2及其四正丁基铵盐和四甲基铵盐ArOPO 3 H - R 4 N +，ArOPO 3 2-2（R 4 N +）的行为。非质子传递溶剂，在不存在或存在越来越多的醇或水的情况下。在没有胺的情况下，在有受阻和不受阻碍的胺，二异丙基乙胺和奎尼丁的存在下研究了反应。反应过程在35°或70°时遵循31 P和11 H NMR光谱法。根据反应物信号强度等于产物信号强度的时间，估计大约一半反应时间的值（±25％）。所述mononitrophenyl酯转移其磷酰基为醇和水从通过经由oxyphosphorane中间体加成-消除机构的双质子酸，和从一价阴离子和二价阴离子通过消除加成机理经由单体偏中间，PO 3 - 。PO的形成3 -更快从二价阴离子比从在乙腈单价阴离子和醇溶液。相反，PO 3 -在水溶液中，单阴离子的产生速率比二价阴离子的产生速率快。从地层中的PO的速率的降低这样的效果的结果3
• Micellar Effects on the Co-catalysis of Magnesium Ion and Imidazole for the Hydrolysis of Phenyl Phosphatosulfate
  作者：Toshio Eiki、Waichiro Tagaki

  DOI：10.1246/bcsj.55.1102

  日期：1982.4

  The effects of Mg2+ ion and imidazole were examined on the hydrolysis of phenyl and p-decylphenyl phosphatosulfate (PPS and DPPS) in the presence of micelle of sodium dodecyl sulfate (SDS). It was observed that Mg2+ ion and imidazole increased the rates of hydrolysis cooperatively and the rate enhancement was much larger in the case of DPPS than in the case of PPS. The difference in the reactivities

  在十二烷基硫酸钠 (SDS) 胶束存在下，研究了 Mg2+ 离子和咪唑对苯基和对癸基苯基磷酸酯硫酸盐（PPS 和 DPPS）水解的影响。观察到Mg2+离子和咪唑协同提高水解速率，并且在DPPS的情况下比在PPS的情况下提高的速率要大得多。根据胶束效应讨论了两种酯的反应性差异。
• Modification method of resins
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0612797A2

  公开（公告）日：1994-08-31

  Provided for resins by the present invention are flame-retarding, thermal stabilization and compatibilization methods, which make use of specific diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptane and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexane, or derivatives thereof. The novel derivatives, polymeric microspheres and the like are also provided.

  本发明为树脂提供了阻燃、热稳定和相容方法，这些方法利用了特定的二胍胺衍生物，主要是 2,5/2,6-双(4,6-二氨基-1,3,5-三嗪-2-基)-双环[2.2.1]庚烷和 1,3/1,4-双(4,6-二氨基-1,3,5-三嗪-2-基)-环己烷或其衍生物。此外，还提供了新型衍生物、聚合物微球等。
• Method for preparing modified resins and their applications
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0698620A1

  公开（公告）日：1996-02-28

  There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin. According to the preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins. By the utilization of these techniques, there can be obtained a flame-retardant material having a good char formability, a thermally stable material whose molded articles can inhibit heat deterioration, a material excellent in miscibility between different kinds of resins, a surface-modified material which is excellent in adhesion and coating properties and the like.

  本发明公开了一种制备改性树脂的方法，该方法包括通过使用以降冰片烯碳胍胺或其衍生物为代表的含降冰片烯基化合物进行热/反应；一种制备环氧改性树脂的方法，该方法包括使上述改性树脂与环氧化物反应的步骤、包括利用改性树脂的阻燃方法、热稳定方法、相容方法和表面改性方法，以及含有改性树脂的涂料树脂组合物和粘合剂树脂组合物。 根据本发明的制备方法，材料几乎不会变质，而且可以在树脂中引入阻燃性、热稳定性、相容性等性能优异的官能团。利用这些技术，可以获得一种具有良好炭化成型性的阻燃材料、一种热稳定性材料（其成型制品可抑制热变质）、一种在不同种类树脂之间具有良好混溶性的材料、一种在粘附性和涂覆性等方面具有良好性能的表面改性材料。
• Crystal structure of a novel tricoordinate vinyliodinane species and evidence for an alkylidenecarbene-iodonium ylide
  作者：Peter J. Stang、Horst Wingert、Atta M. Arif

  DOI：10.1021/ja00257a079

  日期：1987.11