hexamethylcyclotriphosphazene | 6607-30-3

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: hexamethylcyclotriphosphazene
• 英文别名: 2,2,4,4,6,6-hexamethyl-2λ⁵,4λ⁵,6λ⁵-cyclotriphosphazene；2,2,4,4,6,6-Hexamethyl-2λ⁵,4λ⁵,6λ⁵-cyclotriphosphazen；2,2,4,4,6,6-Hexamethyl-symm.-triazatriphosphin；Hexamethyl-cyclotriphosphazatrien；Hexamethyl-cyclotriphosphonitril；Hexamethylcyclotriphosphazatrien；2,2,4,4,6,6-hexamethyl-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
• CAS: 6607-30-3
• 化学式: C₆H₁₈N₃P₃
• 分子量: 225.15
• InChiKey: DEBZEVJNWCNATM-UHFFFAOYSA-N

物化性质

• 密度：
  1.31±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  37.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  hexamethylcyclotriphosphazene 在 potassium fluoride 、 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 17.25h， 生成 1-Phenyl-2-[2,4,6-trimethyl-4,6-bis-(2-oxo-2-phenyl-ethyl)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinin-2-yl]-ethanone
  参考文献：
  名称：

  Gallicano, Keith D.; Oakley, Richard T.; Paddock, Norman L., Canadian Journal of Chemistry, 1981, vol. 59, p. 2654 - 2664

  摘要：

  DOI：
• 作为产物：
  描述：

  BrMe2P=NSiMe3 以90%的产率得到
  参考文献：
  名称：

  WISIAN-NEILSON PATTY; NEILSON H. ROBERT, INORG. CHEM., 1980, 19, NO 7, 1875-1878

  摘要：

  DOI：

文献信息

• Use of Dendrimers to Stimulate Cell Growth
  申请人：Majoral Jean-Pierre

  公开号：US20090142316A1

  公开（公告）日：2009-06-04

  The present invention relates to the use of dendrimers with monophosphonic or bisphosphonic terminations in order to stimulate the growth of cell cultures or to activate cells in culture.

  本发明涉及在细胞培养中使用具有单磷酸或双磷酸端基的树枝状聚合物，以促进细胞培养的生长或激活细胞。
• DENDRIMERS WITH A SACCHARIDE ENDING FOR ANTI-INFLAMMATORY PURPOSES
  申请人：Prandi Jacques

  公开号：US20130274210A1

  公开（公告）日：2013-10-17

  The present invention relates to dendrimers with a monosaccharide, oligosaccharide or polysaccharide terminal group, to their preparation method and their therapeutic uses, notably anti-inflammatory uses.

  本发明涉及具有单糖、寡糖或多糖末端基团的树状分子，其制备方法以及它们的治疗用途，特别是抗炎用途。
• USE OF PHOSPHOROUS-CONTAINING ORGANIC OXYIMIDES AS FLAME RETARDANTS AND/OR AS STABILIZERS FOR PLASTICS, FLAME-RETARDANT AND/OR STABILIZED PLASTIC COMPOSITIONS, METHOD FOR THE PRODUCTION THEREOF, MOULDED PART, PAINT AND COATINGS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

  公开号：US20170260366A1

  公开（公告）日：2017-09-14

  The present invention relates to the use of phosphorous-containing organic oxyimides according to the general formula (I) as flame retardant for plastic materials, as radical generators in plastic materials and/or stabilisers for plastics. In addition, the present invention relates to a flame-retardant plastic material moulding compound in which the previously described phosphorous-containing organic oxyimides are integrated, and also to a method for the production of the previously mentioned plastic material composition. Furthermore, the present invention relates to a moulded article, a paint or a coating from the previously mentioned flame-retardant plastic material composition.

  本发明涉及根据一般式(I)的含磷有机氧亚胺化合物作为塑料材料的阻燃剂，作为塑料材料中的自由基发生剂和/或塑料的稳定剂。此外，本发明涉及一种阻燃塑料材料成型复合物，其中集成了前述的含磷有机氧亚胺化合物，并且涉及一种用于制备前述塑料材料组合物的方法。此外，本发明涉及一种从前述阻燃塑料材料组合物制成的成型制品、涂料或涂层。
• CYCLIC PHOSPHAZENE COMPOUNDS AND USE THEREOF IN ORGANIC LIGHT EMITTING DIODES
  申请人：Fuchs Evelyn

  公开号：US20110172423A1

  公开（公告）日：2011-07-14

  An organic light-emitting diode comprising at least one cyclic phosphazene compound, a light-emitting layer formed from at least one matrix material and at least one emitter material, wherein the at least one matrix material comprises at least one cyclic phosphazene compound, the use of cyclic phosphazene compounds in organic light-emitting diodes and a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode, and selected cyclic phosphazene compounds and processes for preparing them.

  一种有机发光二极管，包括至少一种环状磷氮化合物，由至少一种基质材料和至少一种发光材料形成的发光层，其中至少一种基质材料包括至少一种环状磷氮化合物，在有机发光二极管中使用环状磷氮化合物以及从静态视觉显示单元、移动视觉显示单元和至少一个创新有机发光二极管组成的照明单元中选择的器件，以及选择的环状磷氮化合物和用于制备它们的方法。
• Process For Producing Phosphonitrilic Acid Ester
  申请人：Kuwata Kotaro

  公开号：US20080091050A1

  公开（公告）日：2008-04-17

  A process for producing a cyclic and/or linear phosphonitrilic acid ester from a cyclic and/or linear phosphonitrile dichloride is provided, wherein the reaction time is shorter and the content of monochloro phosphazenes is very small. When phosphonitrile dichloride is reacted with a metal arylolate and/or a metal alcoholate in the presence of a reaction solvent, a metal arylolate and/or a metal alcoholate composed of at least two different metals having different ionization energies is used and also a specific compound is used as a catalyst.

  解决的问题：提供一种从环状和/或线性磷酸腈二氯化物制备环状和/或线性磷氮酸酯的方法，其中反应时间较短，单氯磷氮烷的含量非常小。 解决方案：当磷酸腈二氯化物与金属芳酚醇盐和/或金属醇盐在反应溶剂存在下反应时，使用由至少两种具有不同电离能的金属组成的金属芳酚醇盐和/或金属醇盐，并且还使用特定化合物作为催化剂。

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