3,3,5-trifluoro-5-tridecafluorohexyl-1,2,4-trioxolane | 309260-93-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三氧戊环
• 英文名称: 3,3,5-trifluoro-5-tridecafluorohexyl-1,2,4-trioxolane
• 英文别名: 3,3,5-trifluoro-5-perfluorohexyl-1,,2,4-trioxolane；3,3,5-Trifluoro-5-trideca-fluorohexyl-1,2,4-trioxolane；3,3,5-trifluoro-5-(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)-1,2,4-trioxolane
• CAS: 309260-93-3
• 化学式: C₈F₁₆O₃
• 分子量: 448.061
• InChiKey: DNXRABYTLYWDES-UHFFFAOYSA-N

物化性质

• 沸点：
  119.2±40.0 °C(Predicted)
• 密度：
  1.82±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为反应物：
  描述：

  3,3,5-trifluoro-5-tridecafluorohexyl-1,2,4-trioxolane 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以90%的产率得到全氟-1-庚醇
  参考文献：
  名称：

  摘要：

  Ozonization of perfluoro-1-octene in Freon-113 yields the corresponding ozonide whose catalytic hydrogenation over Pd/C or hydride reduction leads to formation of perfluoroheptanoic acid; the reduction with lithium aluminum hydride gives 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-heptanol. Ozonization of perfluoro-1-octene in Freon-113 containing excess (greater than or equal to3 equiv) alcohol affords the corresponding perfluoroheptanoic acid ester.

  DOI：

  10.1023/a:1012311903712
• 作为产物：
  描述：

  全氟辛烯-1 在 氧气 、 臭氧 作用下， 以 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 2.0h， 生成 3,3,5-trifluoro-5-tridecafluorohexyl-1,2,4-trioxolane
  参考文献：
  名称：

  摘要：

  Ozonization of perfluoro-1-octene in Freon-113 yields the corresponding ozonide whose catalytic hydrogenation over Pd/C or hydride reduction leads to formation of perfluoroheptanoic acid; the reduction with lithium aluminum hydride gives 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-heptanol. Ozonization of perfluoro-1-octene in Freon-113 containing excess (greater than or equal to3 equiv) alcohol affords the corresponding perfluoroheptanoic acid ester.

  DOI：

  10.1023/a:1012311903712

文献信息

• Ozonides of perfluorooct-1-ene and perfluorooct-2-ene
  作者：V. N. Odinokov、V. R. Akhmetova、R. G. Savchenko、M. V. Bazunova、E. A. Paramonov、L. M. Khalilov

  DOI：10.1007/bf02494903

  日期：2000.6

  Ozonides of higher perfluoroalkenes were prepared for the first time by ozonation of perfluorooct-1- and -2-enes in Freon-113. The structures of the resulting compounds were confirmed by C-13 NMR spectroscopy and GLC-mass spectrometry.
• ——
  作者：V. N. Odinokov、V. R. Akhmetova、M. V. Bazunova、R. G. Savchenko、E. A. Paramonov、L. M. Khalilov

  DOI：10.1023/a:1012311903712

  日期：——

  Ozonization of perfluoro-1-octene in Freon-113 yields the corresponding ozonide whose catalytic hydrogenation over Pd/C or hydride reduction leads to formation of perfluoroheptanoic acid; the reduction with lithium aluminum hydride gives 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-heptanol. Ozonization of perfluoro-1-octene in Freon-113 containing excess (greater than or equal to3 equiv) alcohol affords the corresponding perfluoroheptanoic acid ester.