tributyl(hexyl)-λ5-phosphane

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: tributyl(hexyl)-λ5-phosphane
• 化学式: C₁₈H₄₁P
• 分子量: 288.5
• InChiKey: SXOVVXCBUBVHIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Ring alkylation of aniline or an aniline derivative using ionic liquid catalysts
  申请人：Hobbs J. Steven

  公开号：US20070135656A1

  公开（公告）日：2007-06-14

  A process for ring-alkylating aniline or an aniline derivative in which aniline or an aniline derivative is reacted with an alkylating agent in the presence of an ionic liquid which includes a Lewis acid and a quaternary cation, to produce a ring-alkylated alkylaniline or a ring-alkylated aniline derivative. The use of an ionic liquid permits convenient separation of the alkylated reaction product from the reactants.

  一种用于在离子液体的存在下对苯胺或苯胺衍生物进行环烷基化的过程，其中苯胺或苯胺衍生物与烷基化剂在包含路易斯酸和季铵阳离子的离子液体中反应，以产生环烷基化的烷基苯胺或环烷基化的苯胺衍生物。离子液体的使用允许方便地将烷基化反应产物与反应物分离。
• Alkylation of N'-phenyl-N-alkylphenylenediamines in ionic liquid, N'-phenyl-N-alkyl (alkylphenylene) diamines produced thereby, and lubricant compositions containing same
  申请人：Hobbs J. Steven

  公开号：US20070135657A1

  公开（公告）日：2007-06-14

  A process for alkylation of a N′-phenyl-N-alkyl-p-phenylenediamine of specified formula in an ionic liquid unexpectedly produces a N′-phenyl-N-alkyl(alkylphenylene)diamine of a second specified formula. The use of an inorganic liquid permits convenient separation of the alkylated reaction product from the reaction mixture.

  在一种离子液体中，通过烷基化特定化学式的N'-苯基-N-烷基-p-苯二胺的方法，意外地产生了第二个特定化学式的N'-苯基-N-烷基(烷基苯基)二胺。使用无机液体可以方便地将烷基化反应产物与反应混合物分离。
• CATALYTIC DISPROPORTIONATION OF PARAFFINS USING IONIC LIQUIDS
  申请人：UOP LLC

  公开号：US20150005543A1

  公开（公告）日：2015-01-01

  Processes for the disproportionation and isomerization of a hydrocarbon feed using a liquid catalyst comprising an ionic liquid and a carbocation promoter are described. The ionic liquid is unsupported, and the reactions occur at temperatures below about 200° C.

  描述了使用液体催化剂进行烃原料的不均分和异构化的过程，该催化剂包括离子液体和碳阳离子促进剂。该离子液体是无支撑的，并且反应发生在约200°C以下的温度下。
• CATALYTIC ISOMERIZATION OF PENTANE USING IONIC LIQUIDS
  申请人：UOP LLC

  公开号：US20150005542A1

  公开（公告）日：2015-01-01

  Processes for the disproportionation and isomerization of a C 5 hydrocarbon feed using a liquid catalyst comprising an ionic liquid and a halocarbon carbocation promoter are described. The ionic liquid is unsupported, and the reactions occur at temperatures below about 200° C.

  描述了使用液体催化剂进行C5碳氢化合物进料的不均衡反应和异构化反应的过程，该液体催化剂包括离子液体和卤碳卡宾促进剂。该离子液体是不受支撑的，并且反应发生在约200°C以下的温度下。
• Process for Manufacture of Optically Active 2-(Acyloxymethyl)-1,3-Oxathiolanes
  申请人：Peterson John R.

  公开号：US20100143978A1

  公开（公告）日：2010-06-10

  There is provided a process for manufacture of optically-active, 2-(acyloxymethyl)-1,3-oxathiolanes of Formula I comprising a preparation of a racemic compound and an enzyme-catalyzed kinetic resolution of the enantiomers. The invention may further provide for the esterification and racemization of the by-product of the enzymatic reaction. In this manner, 2(R)-(benzoyloxymethyl)-1,3-oxathiolane is prepared as a useful intermediate for manufacture of the anti-HIV drug Apricitabine.

  提供了一种制备光学活性的2-(酰氧甲基)-1,3-噁硫烷酮（式I）的方法，包括制备外消旋化合物和酶催化对映体的动力学分辨。本发明还可以进一步提供酯化和酶催化反应的副产物的外消旋化。通过这种方式，制备出2(R)-(苯甲酰氧甲基)-1,3-噁硫烷酮作为制造抗HIV药物Apricitabine的有用中间体。