N-[bis(dimethylamino)-methyl-λ5-phosphanyl]-N-methylmethanamine

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: N-[bis(dimethylamino)-methyl-λ5-phosphanyl]-N-methylmethanamine
• 化学式: C₇H₂₂N₃P
• 分子量: 179.24
• InChiKey: YJLPRCWMLWLZLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• NOVEL SUPPORTED PHOSPHAZENE CATALYSTS, NOVEL COMPOUNDS FOR THE CATALYSTS, AND USE THEREOF
  申请人：Mitsui Chemicals Polyurethanes, Inc.

  公开号：EP1775301A1

  公开（公告）日：2007-04-18

  There is provided a phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): (wherein n is an integer of 1 to 8 and represents the number of phosphazenium cations, and Zn- is an anion of an active hydrogen compound in a form derived by releasing n protons from an active hydrogen compound having a maximum of 8 active hydrogen atoms. a, b, c and d are each a positive integer of 3 or less. R's represent the same or different hydrocarbon groups having 1 to 10 carbon atoms and two R's located on each common nitrogen atom may be bonded to each other to form a ring structure. R1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms. D is a direct bond or a divalent group capable of bonding N to a support.). The phosphazene-supported catalyst according to the present invention is highly effective to proceed various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. Further, according to the method of the invention, polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.

  本发明提供了一种磷杂蒽支持的催化剂，其中支持物与通式（1）所代表的基团键合： (其中 n 为 1 至 8 的整数，代表磷砷阳离子的数目，Zn- 为活性氢化合物的阴离子，其形式为从最多具有 8 个活性氢原子的活性氢化合物中释放出 n 个质子而得到。a、b、c 和 d 各为 3 或更小的正整数。R 代表具有 1 至 10 个碳原子的相同或不同的烃基，位于每个公共氮原子上的两个 R 可相互键合以形成环状结构。R1 是氢原子或具有 1 至 10 个碳原子的烃基。D 是直接键或能将 N 键合到支持物上的二价基团）。根据本发明的磷烯支撑催化剂对进行各种有机反应非常有效，而且即使在回收和重复使用催化剂后活性也不会降低，因此具有经济优势。此外，根据本发明的方法，可以极其高效地进行环状单体的聚合、取代基的取代、碳-碳键形成反应等。
• Umsetzungsprodukt von olefinisch ungesättigten Verbindungen mit wasserstoffaktiven Verbindungen, Verfahren zu dessen Herstellung und darauf basierende 2-Komponentenlacke
  申请人：HOECHST AKTIENGESELLSCHAFT

  公开号：EP0160824B1

  公开（公告）日：1989-09-06
• SYNTHESIS OF HETERO COMPOUNDS USING DIALKYLCARBONATE QUATERNATION
  申请人：Friesen Cody A.

  公开号：US20120321969A1

  公开（公告）日：2012-12-20

  Methods of preparing hetero ionic complexes, and ionic liquids from bisulfate salts of heteroatomic compounds using dialkylcarbonates as a primary quaternizing reactant are disclosed. Also disclosed are methods of making electrochemical cells comprising the ionic liquids, and an electrochemical cell comprising an alkaline electrolyte and a hetero ionic complex additive.
• METHODS OF PRODUCING SULFATE SALTS OF CATIONS FROM HETEROATOMIC COMPOUNDS AND DIALKYL SULFATES AND USES THEREOF
  申请人：FRIESEN Cody A.

  公开号：US20120323004A1

  公开（公告）日：2012-12-20

  Methods of preparing sulfate salts of heteroatomic compounds using dialkyl sulfates as a primary reactant are disclosed. Also disclosed are methods of making ionic liquids from the sulfate salts of the heteroatomic compound, and electrochemical cells comprising the ionic liquids.
• SYNTHESIS OF HETERO IONIC COMPOUNDS USING DIALKYLCARBONATE QUATERNIZATION
  申请人：Fluidic, Inc.

  公开号：US20170125824A1

  公开（公告）日：2017-05-04

  Methods of preparing hetero ionic complexes, and ionic liquids from bisulfate salts of heteroatomic compounds using dialkylcarbonates as a primary quaternizing reactant are disclosed. Also disclosed are methods of making electrochemical cells comprising the ionic liquids, and an electrochemical cell comprising an alkaline electrolyte and a hetero ionic complex additive.