[3-[(E)-(naphthalen-1-ylhydrazinylidene)methyl]-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [3-[(E)-(naphthalen-1-ylhydrazinylidene)methyl]-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• 化学式: C₄₉H₅₀N₂O₁₀
• 分子量: 826.9
• InChiKey: IQWYAVXTXGWTMD-BAABIVDXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  61
• 可旋转键数：
  29
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  148
• 氢给体数：
  1
• 氢受体数：
  12

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL
  申请人：Zeon Corporation

  公开号：EP3483141A2

  公开（公告）日：2019-05-15

  The present invention relates to: a hydrazine compound represented by formula (3), wherein Ax and Ay have the meanings indicated in claims 1 to 5; a method for producing an optically anisotropic article by (i) obtaining a polymerizable compound by reacting the hydrazine compound with a carbonyl compound, (ii) forming an alignment film on a substrate, and (iii) forming a liquid crystal layer on the alignment film using the polymer obtained by polymerizing the polymerizable compound or a polymerizable composition including the polymerizable compound and an initiator; and a method for producing a polymerizable compound represented by formula (I), by reacting the hydrazine compound with a carbonyl compound represented by formula (4). The film thus obtained has a low melting point, excellent solubility, is capable of being manufactured at low cost, and capable of uniform polarized light conversion across a broad wavelength region.

  本发明涉及一种由式(3)表示的肼化合物，其中Ax和Ay具有权利要求1至5所述的含义；一种生产光学各向异性制品的方法，其方法是：(i)通过使肼化合物与羰基化合物反应获得可聚合化合物，(ii)在基底上形成配位膜，(iii)使用通过聚合可聚合化合物或包括可聚合化合物和引发剂的可聚合组合物获得的聚合物在配位膜上形成液晶层；以及一种通过使肼化合物与式(4)代表的羰基化合物反应生产式(I)代表的可聚合化合物的方法。由此获得的薄膜熔点低、溶解性好、制造成本低，并能在宽波长区域内实现均匀的偏振光转换。
• Polymerizable compound, polymerizable composition, polymer, and optically anisotropic material
  申请人：ZEON CORPORATION

  公开号：US10647794B2

  公开（公告）日：2020-05-12

  The invention provides a polymerizable compound of formula (I), polymerizable composition, polymer, and optically anisotropic article capable of obtaining an optical film having a low melting point, excellent solubility, being manufactured at low cost, and of uniform polarized light conversion across a broad wavelength region. In formula (I): Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—; G1 and G2 are independently a divalent C1-C20 aliphatic group; Z1 and Z2 are independently a C2-C10 alkenyl group substituted with a halogen atom; Ax is a C2-C30 organic group that includes at least one aromatic ring of an aromatic hydrocarbon ring or an aromatic hetero ring; Ay is H, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group; A1 is a trivalent aromatic group; A2 and A3 are independently a divalent C6-C30 aromatic group; and Q1 is H, or a C1-C6 alkyl group.

  本发明提供了一种可聚合的式(I)化合物、可聚合组合物、聚合物和光学各向异性制品，能够获得熔点低、溶解性好、制造成本低、在宽波长区域内偏振光转换均匀的光学薄膜。在式 (I) 中Y1 至 Y6 独立地为化学单键、-O-、-O-C(═O)-、-C(═O)-O-；G1 和 G2 独立地为二价 C1-C20 脂肪族基团；Z1 和 Z2 独立地为被卤原子取代的 C2-C10 烯基；Ax 是 C2-C30 有机基团，其中包括至少一个芳香烃环或芳香杂环；Ay 是 H、C1-C20 烷基、C2-C20 烯基、C3-C12 环烷基；A1 是三价芳香基团；A2 和 A3 独立地是二价 C6-C30 芳香基团；Q1 是 H 或 C1-C6 烷基。
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC BODY
  申请人：Sakamoto Kei

  公开号：US20140142266A1

  公开（公告）日：2014-05-22

  The present invention relates to a polymerizable compound represented by a formula (I). The present invention provides a polymerizable compound, a polymerizable composition, a polymer, and an optically anisotropic article that are capable of obtaining an optical film having a low melting point, having excellent solubility, capable of being manufactured at low cost, and capable of uniform polarized light conversion across a broad wavelength region. [In formula: Y 1 to Y 6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O— etc.; G 1 and G 2 are independently a divalent C1-C20 aliphatic group etc.; Z 1 and Z 2 are independently C2-C10 alkenyl group that is substituted with a halogen atom etc.; A x is a C2-C30 organic group that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring; A y is a hydrogen atom, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group etc.; A 1 is a trivalent aromatic group etc.; A 2 and A 3 are independently a divalent C6-C30 aromatic group etc.; and Q 1 is a hydrogen atom, or a C1-C6 alkyl group etc.]
• INTERMEDIATE FOR MANUFACTURE OF POLYMERIZABLE COMPOUND AND PROCESS FOR MANUFACTURE THEREOF
  申请人：Sakamoto Kei

  公开号：US20140235857A1

  公开（公告）日：2014-08-21

  The present invention pertains to a compound represented by a formula (I) and a method for producing thereof (in the formula, A x is an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, A y is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group, an alkenyl group having 2 to 18 carbon atoms, an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, or the like. A x and A y optionally bond to each other to form a ring, and Q is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like.). According to the invention, provided are a novel compound that makes it possible to produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band can be inexpensively produced in high yield by utilizing the compound according to one aspect of the invention as an intermediate for producing the polymerizable compound, and a method for producing thereof.
• US9207360B2
  申请人：——

  公开号：US9207360B2

  公开（公告）日：2015-12-08