[3-[(E)-[1,3-benzothiazol-2-yl(prop-2-enoyl)hydrazinylidene]methyl]-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [3-[(E)-[1,3-benzothiazol-2-yl(prop-2-enoyl)hydrazinylidene]methyl]-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• 化学式: C₄₉H₄₉N₃O₁₁S
• 分子量: 888.0
• InChiKey: CKFLDRNEDLNPNT-VZIFVVPESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  64
• 可旋转键数：
  30
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  198
• 氢给体数：
  0
• 氢受体数：
  14

文献信息

• Polymerizable compound and optically anisotropic body
  申请人：DIC Corporation

  公开号：US10428032B2

  公开（公告）日：2019-10-01

  The present invention provides a compound represented by the general formula (I), and a polymerizable composition containing the compound. When the polymerizable composition containing the compound represented by the formula (I) is used to form a filmy product, the resulting filmy product exhibits less change over time in phase difference and reverse wavelength dispersion and when the filmy polymer is irradiated with UV light, peeling from a substrate is unlikely to be caused. Further, the invention provides a polymer obtained through polymerization of the polymerizable composition and an optically anisotropic body obtained using the polymer.

  本发明提供了通式（I）所代表的化合物，以及含有该化合物的可聚合组合物。当使用含有通式（I）所代表化合物的可聚合组合物来形成薄膜状产品时，所得到的薄膜状产品的相位差和反向波长色散随时间的变化较小，当用紫外线照射薄膜状聚合物时，不太可能从基材上剥离。此外，本发明还提供了一种通过聚合可聚合组合物而获得的聚合物，以及使用该聚合物获得的光学各向异性体。
• Polymerizable compound, polymerizable composition, polymer, and optically anisotropic material
  申请人：ZEON CORPORATION

  公开号：US10647794B2

  公开（公告）日：2020-05-12

  The invention provides a polymerizable compound of formula (I), polymerizable composition, polymer, and optically anisotropic article capable of obtaining an optical film having a low melting point, excellent solubility, being manufactured at low cost, and of uniform polarized light conversion across a broad wavelength region. In formula (I): Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—; G1 and G2 are independently a divalent C1-C20 aliphatic group; Z1 and Z2 are independently a C2-C10 alkenyl group substituted with a halogen atom; Ax is a C2-C30 organic group that includes at least one aromatic ring of an aromatic hydrocarbon ring or an aromatic hetero ring; Ay is H, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group; A1 is a trivalent aromatic group; A2 and A3 are independently a divalent C6-C30 aromatic group; and Q1 is H, or a C1-C6 alkyl group.

  本发明提供了一种可聚合的式(I)化合物、可聚合组合物、聚合物和光学各向异性制品，能够获得熔点低、溶解性好、制造成本低、在宽波长区域内偏振光转换均匀的光学薄膜。在式 (I) 中Y1 至 Y6 独立地为化学单键、-O-、-O-C(═O)-、-C(═O)-O-；G1 和 G2 独立地为二价 C1-C20 脂肪族基团；Z1 和 Z2 独立地为被卤原子取代的 C2-C10 烯基；Ax 是 C2-C30 有机基团，其中包括至少一个芳香烃环或芳香杂环；Ay 是 H、C1-C20 烷基、C2-C20 烯基、C3-C12 环烷基；A1 是三价芳香基团；A2 和 A3 独立地是二价 C6-C30 芳香基团；Q1 是 H 或 C1-C6 烷基。
• Phase difference plate, circularly polarizing plate, and image display device
  申请人：ZEON CORPORATION

  公开号：US10830935B2

  公开（公告）日：2020-11-10

  A phase difference plate including an optically anisotropic layer obtained by curing a composition (A) containing a polymerizable liquid crystal compound with reverse wavelength dispersion and a polymerizable monomer, wherein the polymerizable liquid crystal compound with reverse wavelength dispersion has a main chain mesogen and a side chain mesogen bonded to the main chain mesogen in the molecule thereof; the main chain mesogen and the side chain mesogen are oriented in different directions, whereby a birefringence Δn of the optically anisotropic layer has reverse wavelength dispersion property; and retardations of a layer obtained by curing a composition (A0) in which the polymerizable monomer in the composition (A) is replaced by the polymerizable liquid crystal compound with reverse wavelength dispersion and retardations of the optically anisotropic layer satisfy specific relationship; and a circularly polarizing plate and a display device including the same.

  一种相位差板，包括通过固化含有具有反向波长色散特性的可聚合液晶化合物和可聚合单体的组合物 (A) 而获得的光学各向异性层，其中具有反向波长色散特性的可聚合液晶化合物在其分子中具有与主链介源键合的主链介源和侧链介源；主链介原和侧链介原在不同方向上定向，因此光学各向异性层的双折射 Δn具有反向波长色散特性；以及通过固化组合物（A0）获得的层的延迟，其中组合物（A）中的可聚合单体被具有反向波长色散特性的可聚合液晶化合物取代，而光学各向异性层的延迟满足特定关系；以及圆偏振片和包括圆偏振片的显示设备。
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL
  申请人：Zeon Corporation

  公开号：EP3266764B1

  公开（公告）日：2019-01-09
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC BODY
  申请人：Sakamoto Kei

  公开号：US20140142266A1

  公开（公告）日：2014-05-22

  The present invention relates to a polymerizable compound represented by a formula (I). The present invention provides a polymerizable compound, a polymerizable composition, a polymer, and an optically anisotropic article that are capable of obtaining an optical film having a low melting point, having excellent solubility, capable of being manufactured at low cost, and capable of uniform polarized light conversion across a broad wavelength region. [In formula: Y 1 to Y 6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O— etc.; G 1 and G 2 are independently a divalent C1-C20 aliphatic group etc.; Z 1 and Z 2 are independently C2-C10 alkenyl group that is substituted with a halogen atom etc.; A x is a C2-C30 organic group that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring; A y is a hydrogen atom, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group etc.; A 1 is a trivalent aromatic group etc.; A 2 and A 3 are independently a divalent C6-C30 aromatic group etc.; and Q 1 is a hydrogen atom, or a C1-C6 alkyl group etc.]