Di(propan-2-yl)phosphanium;chloride

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: Di(propan-2-yl)phosphanium;chloride
• 英文别名: di(propan-2-yl)phosphanium;chloride
• 化学式: C6H16ClP
• 分子量: 154.62
• InChiKey: GFRUKEIXCNUFOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.78
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE-BORANE COMPLEX AND PRODUCTION METHOD THEREFOR, AND METHOD FOR PRODUCING RUTHENIUM COMPLEX CONTAINING N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE AS LIGAND
  申请人：Takasago International Corporation

  公开号：US20190040090A1

  公开（公告）日：2019-02-07

  The purpose of the present invention is to provide an N,N-bis(2-dialkylphosphinoethyl)amine-borane complex which is a ruthenium complex that exhibits excellent catalytic activity in a hydrogenation reaction, etc., and a production method therefor, and a method for efficiently producing a ruthenium complex containing N,N-bis(2-dialkylphosphinoethyl)amine as a ligand. The present invention is capable of efficiently producing an amine-borane complex (3) by reacting an oxazolidinone compound (1) with a dialkylphosphine-borane compound (2) in the presence of a base. The present invention is also capable of efficiently producing a ruthenium complex (5) by reacting the amine-borane complex (3) with a ruthenium compound (4) in the presence of an amine. (In the formula, a solid line, a dashed line, B, C, H, L 1 -L 3 , LG, n, N, O, P, Ru, X, and R 1 -R 10 are as defined in the description.)

  本发明的目的是提供一种N,N-双(2-二烷基膦基乙基)胺硼烷配合物，它是一种在氢化反应中表现出优异催化活性的钌配合物等，以及其生产方法，以及一种有效生产含有N,N-双(2-二烷基膦基乙基)胺作为配体的钌配合物的方法。本发明能够通过在碱存在下将噁唑烷酮化合物(1)与二烷基膦硼烷化合物(2)反应来有效生产胺硼烷配合物(3)。本发明还能够通过在胺存在下将胺硼烷配合物(3)与钌化合物(4)反应来有效生产钌配合物(5)。
• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• [EN] PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, NOVEL CARBONYLATION LIGANDS AND CATALYST SYSTEMS INCORPORATING SUCH LIGANDS<br/>[FR] PROCÉDÉ DE CARBONYLATION DE COMPOSÉS À INSATURATION ÉTHYLÉNIQUE, NOUVEAUX LIGANDS DE CARBONYLATION, ET SYSTÈMES CATALYSEURS COMPRENANT CES LIGANDS
  申请人：LUCITE INT UK LTD

  公开号：WO2010001174A1

  公开（公告）日：2010-01-07

  A novel bidentate catalytic ligand of general formula (I) is described. R represents a hydrocarbyl aromatic structure having at least one aromatic ring to which Q 1 and Q 2 are each linked, via the respective linking group, if present, on available adjacent atoms of the at least one aromatic ring. The groups X 3 and X 4 represent radicals joined via tertiary carbon atoms to the respective atom Q 1 and the groups X 1 and X 2 represent radicals joined via primary, or substituted aromatic ring carbon atom(s) to the respective atom Q 2. A and B represent an optional lower alkylene linking group. Q 1 and Q 2 each represent phosphorus, arsenic or antimony. A process for the carbonylation of ethylenically unsaturated compounds comprising reacting the compound with carbon monoxide in the presence of a source of hydroxyl groups, optionally, a source of anions and catalyst system obtainable by combining a metal of Group 8, 9 or 10 or a compound thereof and the bidentate ligand of general formula (I) is also described.

  描述了一种一般式(I)的新型双齿催化配体。其中，R代表至少具有一个芳香环的烃基芳香结构，其中Q1和Q2分别通过至少一个芳香环上可用的相邻原子的相应连接基（如果存在）连接。基团X3和X4代表通过第三级碳原子连接到相应原子Q1的基团，基团X1和X2代表通过主要或取代的芳香环碳原子连接到相应原子Q2的基团。A和B代表可选的较低烷基连接基。Q1和Q2分别代表磷、砷或锑。还描述了一种用于乙烯基不饱和化合物的羰基化的方法，包括将该化合物与一氧化碳在羟基源的存在下反应，可选地，与阴离子源和由结合第8、9或10族金属或其化合物以及一般式(I)的双齿配体的催化系统获得的催化剂。
• [EN] PHOSPHINYL FORMAMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS PHOSPHINYL FORMAMIDINE, COMPLEXES MÉTALLIQUES, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2015094207A1

  公开（公告）日：2015-06-25

  N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are described. Methods for making N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl formamidine metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds and N2- phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物。还公开了制备N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物的方法。还公开了利用N2-磷酰基甲酰胺金属盐配合物的催化剂体系，以及利用N2-磷酰基胺化合物和N2-磷酰基胺金属盐配合物进行烯烃的寡聚和/或聚合的用途。
• METHOD FOR PRODUCING COPOLYMER OF ALLYL MONOMER HAVING POLAR GROUP
  申请人：The University of Tokyo

  公开号：EP3786196A1

  公开（公告）日：2021-03-03

  The present invention pertains to a method for producing a copolymer of ethylene and an allyl monomer having a polar group represented by general formula (1), or a copolymer of ethylene, an allyl monomer having a polar group represented by general formula (1), and other monomers, wherein the copolymer is produced in the presence of a boron compound having a boron-hydrogen bond or a boron-carbon bond (for example, a compound represented by general formula (2)) by using a metal complex represented by general formula (C1) as a polymerization catalyst (the symbols in the formulas are as described in the description). According to the present invention, a copolymer of ethylene and an allyl monomer can be efficiently produced with high catalytic activity, wherein the copolymer has a polar group and can be used in various applications.

  本发明涉及一种生产乙烯和具有通式(1)表示的极性基团的烯丙基单体的共聚物，或乙烯、具有通式(1)表示的极性基团的烯丙基单体和其他单体的共聚物的方法、其中，该共聚物是在具有硼-氢键或硼-碳键的硼化合物（例如通式（2）所代表的化合物）存在下，通过使用通式（C1）所代表的金属络合物作为聚合催化剂生产的（式中符号如说明中所描述）。根据本发明，可以高效地生产出具有高催化活性的乙烯和烯丙基单体的共聚物，其中共聚物具有极性基团，可用于各种用途。