phenyl 4-isopropoxybenzoate | 304016-62-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: phenyl 4-isopropoxybenzoate
• 英文别名: Phenyl 4-propan-2-yloxybenzoate
• CAS: 304016-62-4
• 化学式: C₁₆H₁₆O₃
• 分子量: 256.301
• InChiKey: JXPABGYSOLKEAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-异丙氧苯甲酸 、 苯硼酸 在 碘苯二乙酸 、 三乙胺 、 N,N'-羰基二咪唑 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以67%的产率得到phenyl 4-isopropoxybenzoate
  参考文献：
  名称：

  通过偶合芳基羧酸和芳基硼酸的无金属合成芳基酯

  摘要：

  通过在PhI（OAc）2和羰基二咪唑存在下偶联芳基羧酸和芳基硼酸，可以轻松合成芳基酯。宽泛的官能团可耐受无金属的反应条件，从而可以高收率得到所需的产物。

  DOI：

  10.1016/j.tetlet.2014.02.079

文献信息

• Curable composition and color filter
  申请人：FUJIFILM Corporation

  公开号：US10175573B2

  公开（公告）日：2019-01-08

  Provided is a colored curable composition having a good chemical resistance, and capable of forming a good colored layer pattern, the colored curable composition including an epoxy group-containing compound, and a phthalocyanine dye having a functional group capable of forming a covalent bond by a reaction with the epoxy group under heating.

  本发明提供了一种具有良好耐化学性并能形成良好彩色图层图案的彩色可固化组合物，该彩色可固化组合物包括一种含环氧基团的化合物，以及一种酞菁染料，其官能团能在加热条件下与环氧基团反应形成共价键。
• CURABLE COMPOSITION AND COLOR FILTER
  申请人：FUJIFILM Corporation

  公开号：US20150316844A1

  公开（公告）日：2015-11-05

  Provided is a colored curable composition having a good chemical resistance, and capable of forming a good colored layer pattern, the colored curable composition including an epoxy group-containing compound, and a phthalocyanine dye having a functional group capable of forming a covalent bond by a reaction with the epoxy group under heating.
• LIQUID CRYSTALLINE EPOXY COMPOUND WITH TERMINAL MESOGEN CONNECTED BY FLEXIBLE LINKAGE AND METHOD FOR PREPARING THE SAME
  申请人：KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20180201835A1

  公开（公告）日：2018-07-19

  Disclosed is a liquid crystalline epoxy compound wherein an epoxy group is positioned at a side chain of the longer direction of a mesogen group and each of the mesogen group and the epoxy group is connected to the center of the molecular structure through a flexible linkage. Since the liquid crystalline epoxy compound includes an epoxy group positioned at a side chain of the longer direction of a mesogen group and each of the mesogen group and the epoxy group is connected to the center of the molecular structure through a flexible linkage, the interaction between the mesogens in a cured resin product occurs significantly without weakening even after curing, thereby improving the heat conductivity of the resin compound through the active heat transfer between the mesogens.
• Metal-free synthesis of aryl esters by coupling aryl carboxylic acids and aryl boronic acids
  作者：Jayaraman Sembian Ruso、Nagappan Rajendiran、Rajendran Senthil Kumaran

  DOI：10.1016/j.tetlet.2014.02.079

  日期：2014.4

  A facile synthesis of aryl esters is developed by coupling aryl carboxylic acids and aryl boronic acids in the presence of PhI(OAc)2 and carbonyl diimidazole. A wide range of functional groups were tolerant to the metal-free reaction condition that led to the desired products in good yields.

  通过在PhI（OAc）2和羰基二咪唑存在下偶联芳基羧酸和芳基硼酸，可以轻松合成芳基酯。宽泛的官能团可耐受无金属的反应条件，从而可以高收率得到所需的产物。