[4-[2-[[4-[3-(3-Sulfanylpropylsulfanyl)propoxy]phenoxy]methoxy]ethyl]phenyl] 4-[3-(3-sulfanylpropylsulfanyl)propoxy]benzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [4-[2-[[4-[3-(3-Sulfanylpropylsulfanyl)propoxy]phenoxy]methoxy]ethyl]phenyl] 4-[3-(3-sulfanylpropylsulfanyl)propoxy]benzoate
• 英文别名: [4-[2-[[4-[3-(3-sulfanylpropylsulfanyl)propoxy]phenoxy]methoxy]ethyl]phenyl] 4-[3-(3-sulfanylpropylsulfanyl)propoxy]benzoate
• 化学式: C₃₄H₄₄O₆S₄
• 分子量: 677.0
• InChiKey: LSRHYEHWOJFTHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  44
• 可旋转键数：
  25
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  116
• 氢给体数：
  2
• 氢受体数：
  10

文献信息

• POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, AND ANISOTROPIC OPTICAL BODY, PHASE DIFFERENCE FILM, ANTIREFLECTIVE FILM, AND LIQUID CRYSTAL DISPLAY ELEMENT FABRICATED USING COMPOSITION
  申请人：DIC Corporation

  公开号：EP3072911A1

  公开（公告）日：2016-09-28

  An object of the present invention is to provide a polymerizable liquid crystal composition with which two characteristics of smoothness of a surface of an anisotropic optical body and orientation properties of liquid crystals can be simultaneously improved, when preparing an anisotropic optical body to be obtained by photopolymerization of the polymerizable liquid crystal composition. Specifically, an object of the present invention is to provide a polymerizable liquid crystal composition containing specific polymerizable compounds and a fluorine-based surfactant. In addition, an anisotropic optical body, a retardation film, an antireflective film, and a liquid crystal display element prepared using the polymerizable liquid crystal composition of the present invention are also provided.

  本发明的目的是提供一种可聚合液晶组合物，在制备通过光聚合可聚合液晶组合物获得的各向异性光学体时，利用该组合物可以同时改善各向异性光学体表面的光滑度和液晶的取向特性这两个特性。具体来说，本发明的目的是提供一种含有特定可聚合化合物和氟基表面活性剂的可聚合液晶组合物。此外，还提供了使用本发明的可聚合液晶组合物制备的各向异性光学体、延缓膜、抗反射膜和液晶显示元件。
• COMPOUND CONTAINING MESOGENIC GROUP, AND MIXTURE, COMPOSITION, AND OPTICALLY ANISOTROPIC BODY USING SAID COMPOUND
  申请人：DIC Corporation

  公开号：EP3088426A1

  公开（公告）日：2016-11-02

  The present invention relates to a compound containing a mesogenic group, which includes a silicon compound at a low concentration, a polymerizable compound containing the mesogenic group, a mixture and a composition using these compounds, a polymerizable mixture having the polymerizable compound, and a polymer, an optically anisotropic body, and a phase difference film using the polymerizable composition. According to the present invention, it is possible to obtain the optically anisotropic body and the phase difference film having satisfactory scratch resistance and adhesion, by using the polymerizable composition composed of the compound containing a mesogenic group, which includes a silicon compound at a low concentration. The polymer obtained by polymerizing the polymerizable liquid crystal composition of the present invention in a state where the composition is horizontally aligned, vertically aligned, or aligned in a hybrid manner or aligned in a cholesteric manner can be used as the optically anisotropic body having alignment performance, or as an optical compensation film, a phase difference film, a wide viewing angle film, a luminance-enhancing film, a reflective film, and a polarizing film.

  本发明涉及一种含有介原基的化合物，其中包括低浓度硅化合物、含有介原基的可聚合化合物、使用这些化合物的混合物和组合物、含有可聚合化合物的可聚合混合物以及聚合物、光学各向异性体和使用可聚合组合物的相位差薄膜。 根据本发明，通过使用由含有中生基的化合物组成的可聚合组合物（其中包括低浓度的硅化合物），可以获得具有令人满意的抗划伤性和粘附性的光学各向异性体和相位差膜。 本发明的可聚合液晶组合物在水平排列、垂直排列、混合排列或胆固醇排列的状态下聚合得到的聚合物可用作具有排列性能的光学各向异性体，或用作光学补偿膜、相位差膜、广视角膜、亮度增强膜、反射膜和偏振膜。
• POLYMERIZABLE COMPOSITION AND OPTICALLY ANISOTROPIC BODY USING SAME
  申请人：DIC Corporation

  公开号：EP3246340A1

  公开（公告）日：2017-11-22

  The present invention provides a polymerizable composition containing a specific polymerizable compound and a fluorine-based surfactant having a specific polyoxyalkylene skeleton and having specific molecular weight. The invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable composition of the present invention. The present invention is useful because, when an optically anisotropic body is produced by photo-polymerization of the polymerizable composition, three features including the leveling properties of the surface of the optically anisotropic body, offset onto the substrate, and liquid crystal alignment can be improved simultaneously.

  本发明提供了一种可聚合组合物，该组合物含有特定的可聚合化合物和具有特定聚氧亚烷基骨架并具有特定分子量的氟基表面活性剂。本发明还提供了使用本发明的可聚合组合物生产的光学各向异性体、延缓膜、抗反射膜和液晶显示装置。本发明之所以有用，是因为当通过可聚合组合物的光聚合作用生产出光学各向异性体时，可同时改善光学各向异性体表面的平整性、偏移到基板上的偏移量和液晶排列等三个特性。
• US20140256896A1
  申请人：——

  公开号：US20140256896A1

  公开（公告）日：2014-09-11
• POLYMERIZABLE COMPOSITION SOLUTION AND OPTICALLY ANISOTROPIC BODY INCLUDING THE SAME
  申请人：DIC CORPORATION

  公开号：US20160115338A1

  公开（公告）日：2016-04-28

  The present invention provides a polymerizable composition solution that has good storage stability and allows a polymerizable compound in the polymerizable composition to be aligned well with no defects after application to a base and removal of a solvent by a drying process and also provides an optically anisotropic body that includes the solution and has good alignment without any defects. The present invention provides a solution containing a polymerizable composition and an organic solvent, wherein the polymerizable composition contains 90 mass % or more of a polymerizable compound intramolecularly having a 2-methyl-1,4-phenylene group as represented by general formula (1) and provides an optically anisotropic body including the solution.