bis(4-decylphenyl)diazene | 37593-00-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: bis(4-decylphenyl)diazene
• 英文别名: p,p'-Di-n-decyl-azobenzol
• CAS: 37593-00-3
• 化学式: C₃₂H₅₀N₂
• 分子量: 462.762
• InChiKey: BDKMJLSJFJTBOM-JEIPZWNWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.47
• 重原子数：
  34.0
• 可旋转键数：
  20.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  4-癸基苯胺 在 吡啶 、 氧气 、 copper(l) chloride 作用下， 反应 24.0h， 以80%的产率得到bis(4-decylphenyl)diazene
  参考文献：
  名称：

  The use of thermotropic liquid crystals in organometallic chemistry. Synthesis of new mercury, silver and gold complexes with 4,4′-disubstituted azob

  摘要：

  Liquid crystalline 4-XC6H4N=NC6H4X-4' [X = C4H9 (1a), C10H21 (1b), OC4H9 (1c), OC8H17 (1d)] can be easily prepared in high yields from the corresponding anilines. In order to study the influence of metals on the thermal properties of these materials, we have obtained adducts [AuCl3(4-C4H9OC6H4N=NC6H4OC4H9-4')] (2) and [Ag(OClO3)L2] [L = 4-XC6H4N=NCH4X-4'; X = OC4H9 (3a), OC8H17 (3b)]. The silver adducts show thermotropic behaviour. Mercuriation of dialkylazobenzenes 1a-b takes place with [Hg(OAc)2] and LiCl to give [Hg(R)Cl] [R = C6H3(N=NC6H4X-4')-2, X-5; X = C4H9 (bpap) (4a), C10H21 (dpap) (4b)] while dialkoxyazobenzenes 1c-d require [Hg(OOCCF3)2] to obtain [Hg(R)Cl] [R = C6H3(N=NC6H4X-4')-2, X-5, X = OC4H9 (bxpap) (4c), OC8H17 (4d)]. 4a-c react with NaI to give [HgR2] [R = bpap (5a), dpap (5b), bxpap (5c), oxpap (5d)]. Both chloroaryl-, 4a and 4c, and diaryl-mercurials, 5a and 5c, act readily as transmetallating agents towards [Me4N] [AuCl4] in the presence of [Me4N]Cl to give [Au(eta2-R)Cl2] [R = bpap (6a), bxpap (6b)]. After reaction of [AuCl3(tht)] (tht = tetrahydrothiophene) with [Me4N]Cl and 4b (1:2:1), [Me4N][Au(dpap)Cl3] (7) can be isolated. C-H activation of acetone by 6a-b leads to [Au(eta2-R){CH2C(O)Me}Cl][R = bpap (8a), bxpap (8b)]. None of the complexes 4-8 shows mesomorphic behaviour.

  DOI：

  10.1016/0022-328x(94)87107-8

文献信息

• PHOTORESPONSIVE MATERIAL, ADHESIVE, OPTICAL SWITCHING MATERIAL, TONER, AND IMAGE FORMING METHOD
  申请人：Konica Minolta, Inc.

  公开号：US20210332272A1

  公开（公告）日：2021-10-28

  A composition includes an isomerized polymer containing a structural unit containing an isomerized structure and an isomerized low molecular weight compound, the composition being fluidized by light irradiation from a solid state and being reversibly non-fluidized.

  一种组合物包括含有异构化结构单元和异构化低分子量化合物的异构化聚合物，该组合物通过固态光照而变为流动状态，并可可逆地变为非流动状态。
• TONER AND IMAGE FORMATION METHOD
  申请人：KONICA MINOLTA, INC.

  公开号：US20180217518A1

  公开（公告）日：2018-08-02

  The present invention provides means for improving the softening rate in photoirradiation and image fixation property. The toner according to the present invention includes an azobenzene derivative represented by the following chemical formula (1), and in the chemical formula (1), R 1 to R 10 in the following are groups defined in claim 1.

  本发明提供了提高光照软化速率和图像固定性能的方法。根据本发明的调色剂包括以下化学式（1）所表示的偶氮苯衍生物，在化学式（1）中，R1至R10如下所述是权利要求1中定义的基团。
• Toner and image formation method
  申请人：KONICA MINOLTA, INC.

  公开号：US10324391B2

  公开（公告）日：2019-06-18

  The present invention provides means for improving the softening rate in photoirradiation and image fixation property. The toner according to the present invention includes an azobenzene derivative represented by the following chemical formula (1), and in the chemical formula (1), R1 to R10 in the following are groups defined in claim 1.

  本发明提供了提高光辐射软化率和图像固定性能的方法。 根据本发明的调色剂包括由以下化学式（1）表示的偶氮苯衍生物，在化学式（1）中，R1 至 R10 是权利要求 1 中定义的基团。
• The use of thermotropic liquid crystals in organometallic chemistry. Synthesis of new mercury, silver and gold complexes with 4,4′-disubstituted azob
  作者：Jose' Vicente、María Dolores Bermúdez、Francisco J. Carrión、Ginés Martínez-Nicolas

  DOI：10.1016/0022-328x(94)87107-8

  日期：1994.10

  Liquid crystalline 4-XC6H4N=NC6H4X-4' [X = C4H9 (1a), C10H21 (1b), OC4H9 (1c), OC8H17 (1d)] can be easily prepared in high yields from the corresponding anilines. In order to study the influence of metals on the thermal properties of these materials, we have obtained adducts [AuCl3(4-C4H9OC6H4N=NC6H4OC4H9-4')] (2) and [Ag(OClO3)L2] [L = 4-XC6H4N=NCH4X-4'; X = OC4H9 (3a), OC8H17 (3b)]. The silver adducts show thermotropic behaviour. Mercuriation of dialkylazobenzenes 1a-b takes place with [Hg(OAc)2] and LiCl to give [Hg(R)Cl] [R = C6H3(N=NC6H4X-4')-2, X-5; X = C4H9 (bpap) (4a), C10H21 (dpap) (4b)] while dialkoxyazobenzenes 1c-d require [Hg(OOCCF3)2] to obtain [Hg(R)Cl] [R = C6H3(N=NC6H4X-4')-2, X-5, X = OC4H9 (bxpap) (4c), OC8H17 (4d)]. 4a-c react with NaI to give [HgR2] [R = bpap (5a), dpap (5b), bxpap (5c), oxpap (5d)]. Both chloroaryl-, 4a and 4c, and diaryl-mercurials, 5a and 5c, act readily as transmetallating agents towards [Me4N] [AuCl4] in the presence of [Me4N]Cl to give [Au(eta2-R)Cl2] [R = bpap (6a), bxpap (6b)]. After reaction of [AuCl3(tht)] (tht = tetrahydrothiophene) with [Me4N]Cl and 4b (1:2:1), [Me4N][Au(dpap)Cl3] (7) can be isolated. C-H activation of acetone by 6a-b leads to [Au(eta2-R)CH2C(O)Me}Cl][R = bpap (8a), bxpap (8b)]. None of the complexes 4-8 shows mesomorphic behaviour.