1-methyl-trans-decahydro-4-quinolinone | 1874-74-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉类
• 英文名称: 1-methyl-trans-decahydro-4-quinolinone
• 英文别名: methyl-1 oxo-4 trans-decahydroquinoleine；N-methyl-4-decahydroquinolone；(+/-)-1-methyl-(4ar,8at)-octahydro-quinolin-4-one；(+/-)-1-Methyl-(4ar,8at)-octahydro-chinolin-4-on；(4aS,8aS)-1-methyl-2,3,4a,5,6,7,8,8a-octahydroquinolin-4-one
• CAS: 1874-74-4；24616-41-9；119433-54-4
• 化学式: C₁₀H₁₇NO
• 分子量: 167.251
• InChiKey: RITANGGXLSWSNG-IUCAKERBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-methyl-trans-decahydro-4-quinolinone 在 对甲苯磺酸 bis(methoxy-2 ethoxy)-aluminodihydrure de sodium 作用下， 以 正己烷 、 甲苯 、 苯 为溶剂， 反应 120.0h， 生成 phenylamino-4 methyl-1 trans-decahydroquinoleine
  参考文献：
  名称：

  Prost; Van Cromphaut; Verstraeten, European Journal of Medicinal Chemistry, 1980, vol. 15, # 3, p. 215 - 222

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 、 水 、 甲胺 作用下， 生成 1-methyl-trans-decahydro-4-quinolinone
  参考文献：
  名称：

  炔丙二醇，十二烷基苯醌和十二氢喹啉衍生物，II炔基-4，炔基-4和烷基-4-十氢喹啉-4被N取代† ‡

  摘要：

  作者描述了十氢-4-喹啉酮和N-取代的4-炔基-，4-烯丙基-和4-烷基十氢-4-喹啉醇的合成，并讨论了这些化合物的立体化学问题。

  DOI：

  10.1002/hlca.19750580106

文献信息

• Dérivés propargyliques, XII et dérivés de la décahydroquinoléine, II Alkynyl-4, alkényl-4 et alkyl-4-décahydroquinolinols-4 N-substitués
  作者：Maurice Prost、Marcel Urbain、André Schumer、Christian Houben、Clément Van Meerbeeck

  DOI：10.1002/hlca.19750580106

  日期：——

  The authors describe the synthesis of decahydro-4-quinolinones and N-substituted 4-alkynyl-, 4-allyl- and 4-alkyldecahydro-4-quinolinols and discuss the stereochemical problems of this compounds.

  作者描述了十氢-4-喹啉酮和N-取代的4-炔基-，4-烯丙基-和4-烷基十氢-4-喹啉醇的合成，并讨论了这些化合物的立体化学问题。
• Stereochemistry of nitrogen heterocycles. 66. Synthesis and x-ray diffraction analysis of C(4)-epimeric 1-methyl-trans-decahydro-4-quinolinols
  作者：G. S. Litvinenko、V. V. Artyukhina、T. B. Volzhenina、O. V. Shiganakova、L. A. Isakova、A. A. Espenbetov、Yu. T. Struchkov

  DOI：10.1007/bf00755693

  日期：1988.5
• Prost; Van Cromphaut; Verstraeten, European Journal of Medicinal Chemistry, 1980, vol. 15, # 3, p. 215 - 222
  作者：Prost、Van Cromphaut、Verstraeten、et al.

  DOI：——

  日期：——
• Fuel economy and life-cycle cost analysis of a fuel cell hybrid vehicle
  作者：Kwi Seong Jeong、Byeong Soo Oh

  DOI：10.1016/s0378-7753(01)00965-x

  日期：2002.3

  The most promising vehicle engine that can overcome the problem of present internal combustion is the hydrogen fuel cell. Fuel cells are devices that change chemical energy directly into electrical energy without combustion. Pure fuel cell vehicles and fuel cell hybrid vehicles (i.e. a combination of fuel cell and battery) as energy sources are studied. Considerations of efficiency, fuel economy, and the characteristics of power output in hybridization of fuel cell vehicle are necessary, In the case of Federal Urban Driving Schedule (FUDS) cycle simulation, hybridization is more efficient than a pure fuel cell vehicle. The reason is that it is possible to capture regenerative braking energy and to operate the fuel cell system within a more efficient range by using battery.Life-cycle cost is largely affected by the fuel cell size, fuel cell cost, and hydrogen cost. When the cost of fuel cell is high, hybridization is profitable, but when the cost of fuel cell is less than 400 US$/kW. a pure fuel cell vehicle is more profitable. (C) 2002 Elsevier Science B.V. All rights reserved.