4-[(4-bromophenyl)diazenyl]-N,N-bis[2-(oxan-2-yloxy)ethyl]aniline | 181425-61-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 4-[(4-bromophenyl)diazenyl]-N,N-bis[2-(oxan-2-yloxy)ethyl]aniline
• CAS: 181425-61-6
• 化学式: C₂₆H₃₄BrN₃O₄
• 分子量: 532.478
• InChiKey: AIBRGWHHVPTNOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  34
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  64.9
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4-[(4-bromophenyl)diazenyl]-N,N-bis[2-(oxan-2-yloxy)ethyl]aniline 、 二(三甲苯基)氟化硼 在 pyridinium salt of p-toluenesulfonic acid 作用下， 以 乙醇 为溶剂， 生成 2-[4-[[4-bis(2,4,6-trimethylphenyl)boranylphenyl]diazenyl]-N-(2-hydroxyethyl)anilino]ethanol
  参考文献：
  名称：

  Polyurethanes containing boron chromophores as sidechains for nonlinear optics

  摘要：

  An axo-dye containing dimesityl boron as the electron acceptor group is synthesized and incorporated as side chains in polyurethane matrices. These new polymers have been poled under an external electrical field by the corona technique. They exhibit high nonlinear response and a remarkable temporal stability. It appears that the poling time is a crucial parameter not only in terms of obtaining a good second harmonic response but also in the temporal stability. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s0009-2614(97)88019-0

文献信息

• Polyurethanes containing boron chromophores as sidechains for nonlinear optics
  作者：Catherine Branger、Minh Lequan、Rose Marie Lequan、Maryanne Large、François Kajzar

  DOI：10.1016/s0009-2614(97)88019-0

  日期：1997.6

  An axo-dye containing dimesityl boron as the electron acceptor group is synthesized and incorporated as side chains in polyurethane matrices. These new polymers have been poled under an external electrical field by the corona technique. They exhibit high nonlinear response and a remarkable temporal stability. It appears that the poling time is a crucial parameter not only in terms of obtaining a good second harmonic response but also in the temporal stability. (C) 1997 Elsevier Science B.V.