Cyclohexyl(cyclohexylphosphanyl)phosphane

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: Cyclohexyl(cyclohexylphosphanyl)phosphane
• 化学式: C₁₂H₂₄P₂
• 分子量: 230.27
• InChiKey: YYYZOVDOKPPSTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Phosphorus bridged metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20050239981A1

  公开（公告）日：2005-10-27

  This invention relates to metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is a substituted or unsubstituted indenyl ligand that is bonded to Y through the two position of the indenyl ring; A is bonded to Y, and is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E; Y is a phosphorus containing group that is bonded to both E and A, and is bonded via the phosphorus atom to E; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.

  本发明涉及由以下式表示的金属环化合物：其中M是3、4、5或6族过渡金属原子，或镧系金属原子，或锕系金属原子；E是通过茚环的2位与Y键合的取代或未取代的茚基配体；A与Y键合，可以是取代或未取代的环戊二烯基配体、取代或未取代的杂环戊二烯基配体、取代或未取代的茚基配体、取代或未取代的杂茚基配体、取代或未取代的芴基配体、取代或未取代的杂芴基配体或其他单负离子配体，或者A可以独立地被定义为E；Y是含磷基团，通过磷原子与E和A键合；X是独立的单价阴离子配体，或者两个X连接并与金属原子结合形成金属环，或两个X连接形成螯合配体、二烯配体或烷基亚胺配体。
• US7214746B2
  申请人：——

  公开号：US7214746B2

  公开（公告）日：2007-05-08