4-{[4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoyl]oxy}-2-methylphenyl 4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoate | 853993-07-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-{[4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoyl]oxy}-2-methylphenyl 4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoate
• 英文别名: [3-methyl-4-[4-[6-oxo-6-(1-prop-2-enoyloxypropan-2-yloxy)hexoxy]benzoyl]oxyphenyl] 4-[6-oxo-6-(1-prop-2-enoyloxypropan-2-yloxy)hexoxy]benzoate
• CAS: 853993-07-4
• 化学式: C₄₅H₅₂O₁₄
• 分子量: 816.899
• InChiKey: PEWQUBPMBOCQMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  59
• 可旋转键数：
  32
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  176
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  2-[(6-Bromohexanoyl)oxy]propyl acrylate 、 2-methyl-1,4-phenylene bis(4-hydroxybenzoate) 、 potassium carbonate 、 盐酸 在 乙醚 、 Sodium sulfate-III 、 silica 作用下， 以 丁酮 为溶剂， 反应 16.0h， 以to give nearly pure 4-{[4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoyl]oxy}-2-methylphenyl 4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoate as slightly yellow oil的产率得到4-{[4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoyl]oxy}-2-methylphenyl 4-({6-[2-(acryloyloxy)-1-methylethoxy]-6-oxohexyl}oxy)benzoate
  参考文献：
  名称：

  Additive components for liquid crystalline materials

  摘要：

  本发明涉及一种介向性、可交联混合物，包括（i）至少一种可交联液晶化合物组成的可交联液晶宿主化合物，以及（ii）至少一种手性或无手性的棒状添加剂组分，其中所述添加剂组分具有刚性核心，包括至少两个融合或连接的、可选取代的、非芳香性、芳香性、环烷基或杂环基团，并且包括至少一个可选取代的烷基残基和至少一个可聚合基团，所述添加剂组分的向等向态的转变温度为40℃或更低。本发明还涉及用于制备这些混合物的新型手性或无手性棒状添加剂化合物，以及以弹性体、聚合物凝胶、聚合物网络或聚合物薄膜形式出现的本发明所述混合物，以及由这些混合物制备的聚合物网络和液晶聚合物薄膜，以及包括由这些混合物制备的聚合物网络和液晶聚合物薄膜的光学或电光组件。此外，本发明还涉及将手性或无手性棒状化合物用作可交联液晶混合物的组分，以制备定向液晶聚合物，液晶混合物包括这些化合物，以及由这些液晶混合物制备的液晶聚合物和液晶聚合物网络，以及包括这些化合物的液晶器件的使用。

  公开号：

  US08105662B2

文献信息

• Additive Components for Liquid Crystalline Materials
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20070257230A1

  公开（公告）日：2007-11-08

  The present invention relates to mesogenic, cross-linkable mixtures comprising (i) a cross-linkable liquid crystalline host compound comprising at least one cross-linkable liquid crystalline compound, and (ii) at least one chiral or achiral rod shaped additive component, wherein said additive component has a rigid core and comprises at least two fused or linked, optionally substituted, non-aromatic, aromatic, carbocyclic or heterocyclic groups, and also comprises at least one optionally substituted alkyl residue, and at least one polymerizable group and wherein the additive component has a transition temperature to the isotropic state of 40° C. or lower. The invention also relates to the novel chiral or achiral rod-shaped additive compounds used for the preparation of these mixtures, to mixtures according to the invention in form of an elastomer, polymer gel, polymer network or polymer film, to polymer networks and liquid crystalline polymer films prepared from these mixtures and to optical or electrooptical components comprising polymer networks and liquid crystalline polymer films prepared from such mixtures. Further, the invention relates to the use of the chiral or achiral rod shaped compounds as components of a cross-linkable liquid crystalline mixture in the production of orientated liquid crystalline polymers, to liquid crystalline mixtures comprising these compounds, to liquid crystalline polymers and liquid crystalline polymer networks prepared from such liquid crystalline mixtures, and to liquid crystalline devices comprising these compounds.

  本发明涉及到一种向列相交联混合物，包括（i）至少包含一种可交联向列相化合物的可交联向列相宿主化合物，和（ii）至少一种手性或无手性的棒状添加剂组分，其中该添加剂组分具有刚性的核心，包括至少两个融合或连接的、可选地取代的非芳香族、芳香族、碳环族或杂环族基团，同时包括至少一个可选地取代的烷基残基和至少一个可聚合基团，且该添加剂组分具有向等向态转变的转变温度为40℃或更低。本发明还涉及用于制备这些混合物的新手性或无手性棒状添加剂化合物，以及以弹性体、聚合物凝胶、聚合物网络或聚合物膜形式的本发明的混合物、从这些混合物制备的聚合物网络和向列相聚合物膜、以及包含从这些混合物制备的聚合物网络和向列相聚合物膜的光学或电光组件。此外，本发明还涉及将手性或无手性棒状化合物用作可交联向列相混合物的组分，用于生产定向向列相聚合物，液晶混合物包括这些化合物，从这些液晶混合物制备的液晶聚合物和液晶聚合物网络，以及包含这些化合物的液晶装置的使用。
• Additive components for liquid crystalline materials
  申请人：Rolic AG

  公开号：US08105662B2

  公开（公告）日：2012-01-31

  The present invention relates to mesogenic, cross-linkable mixtures comprising (i) a cross-linkable liquid crystalline host compound comprising at least one cross-linkable liquid crystalline compound, and (ii) at least one chiral or achiral rod shaped additive component, wherein said additive component has a rigid core and comprises at least two fused or linked, optionally substituted, non-aromatic, aromatic, carbocyclic or heterocyclic groups, and also comprises at least one optionally substituted alkyl residue, and at least one polymerizable group and wherein the additive component has a transition temperature to the isotropic state of 40° C. or lower. The invention also relates to the novel chiral or achiral rod-shaped additive compounds used for the preparation of these mixtures, to mixtures according to the invention in form of an elastomer, polymer gel, polymer network or polymer film, to polymer networks and liquid crystalline polymer films prepared from these mixtures and to optical or electrooptical components comprising polymer networks and liquid crystalline polymer films prepared from such mixtures. Further, the invention relates to the use of the chiral or achiral rod shaped compounds as components of a cross-linkable liquid crystalline mixture in the production of orientated liquid crystalline polymers, to liquid crystalline mixtures comprising these compounds, to liquid crystalline polymers and liquid crystalline polymer networks prepared from such liquid crystalline mixtures, and to liquid crystalline devices comprising these compounds.

  本发明涉及一种介向性、可交联混合物，包括（i）至少一种可交联液晶化合物组成的可交联液晶宿主化合物，以及（ii）至少一种手性或无手性的棒状添加剂组分，其中所述添加剂组分具有刚性核心，包括至少两个融合或连接的、可选取代的、非芳香性、芳香性、环烷基或杂环基团，并且包括至少一个可选取代的烷基残基和至少一个可聚合基团，所述添加剂组分的向等向态的转变温度为40℃或更低。本发明还涉及用于制备这些混合物的新型手性或无手性棒状添加剂化合物，以及以弹性体、聚合物凝胶、聚合物网络或聚合物薄膜形式出现的本发明所述混合物，以及由这些混合物制备的聚合物网络和液晶聚合物薄膜，以及包括由这些混合物制备的聚合物网络和液晶聚合物薄膜的光学或电光组件。此外，本发明还涉及将手性或无手性棒状化合物用作可交联液晶混合物的组分，以制备定向液晶聚合物，液晶混合物包括这些化合物，以及由这些液晶混合物制备的液晶聚合物和液晶聚合物网络，以及包括这些化合物的液晶器件的使用。
• Optical isomer
  申请人：DIC Corporation

  公开号：US10655066B2

  公开（公告）日：2020-05-19

  The problem that the present invention is to solve is to provide an optical film that has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state. The present invention provides an optical film containing a structural unit derived from a specific compound, that is, an optical film containing a structural unit derived from a compound represented by the general formula (I), which has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state, and also provides a display device including the optical film.

  本发明要解决的问题是提供一种光学薄膜，它具有较少的排列缺陷，并且在高温状态下不易引起光学特性的变化。 本发明提供了一种含有由特定化合物衍生的结构单元的光学薄膜，即含有由通式（I）表示的化合物衍生的结构单元的光学薄膜，该光学薄膜具有较少的排列缺陷，并且在高温状态下不易引起光学特性的变化，本发明还提供了一种包括该光学薄膜的显示装置。
• ADDITIVE COMPONENTS FOR LIQUID CRYSTALLINE MATERIALS
  申请人：Rolic AG

  公开号：EP1689827B1

  公开（公告）日：2008-07-09
• OPTICAL ISOMER
  申请人：DIC Corporation

  公开号：US20180037819A1

  公开（公告）日：2018-02-08

  The problem that the present invention is to solve is to provide an optical film that has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state. The present invention provides an optical film containing a structural unit derived from a specific compound, that is, an optical film containing a structural unit derived from a compound represented by the general formula (I), which has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state, and also provides a display device including the optical film.